Temperature and pressure are fundamental physical parameters in the field of materials science, making their monitoring of utmost significance for scientists and engineers. Here, the NaSrY(MoO4):0.02Er/0.01Tm/0.15Yb nanophosphor is developed as an optical sensor material. Under 975 nm laser excitation, the upconversion characteristics and optical detection performance of the multifunctional sensing platform of temperature and pressure (vacuum) are investigated. We have successfully developed a novel detection platform that enables optical detection of pressure (vacuum) and temperature. This platform utilizes thermally coupled levels (TCLs) and non-TCLs of Er and Tm to achieve ratiometric detection. The multimodal optical temperature and pressure detection based on TCLs and non-TCLs is successfully realized by using different emission bands of double emission centers, which makes it possible for self-referencing optical temperature and pressure measurement modes. These results indicate that the developed nanophosphor is a promising candidate for optical sensors, and our findings suggest potential strategies for modulating the sensor properties of luminescent materials doped with rare-earth ions.
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http://dx.doi.org/10.1021/acsami.4c00313 | DOI Listing |
Angew Chem Int Ed Engl
January 2025
KAIST - Korea Advanced Institute of Science and Technology, Department of Chemistry, Center for Nanomaterials and Chemical Reaction, IBS, 373-1, Guseong Dong, Yuseong Gu, 305-701, Daejeon, KOREA, REPUBLIC OF.
Understanding how TiO2 interacts with CO2 at the molecular level is crucial in the CO2 reduction toward value-added energy sources. Here, we report in-situ observations of the CO2 activation process on the reduced TiO2(110) surface at room temperature using ambient pressure scanning tunneling microscopy. We found that oxygen vacancies (Vo) diffuse dynamically along the bridging oxygen (Obr) rows of the TiO2(110) surface under ambient CO2(g) environments.
View Article and Find Full Text PDFSci Data
January 2025
Institute of Physics, Faculty of Science, Pavol Jozef Šafárik University in Košice, Park Angelinum 9, 041 54, Košice, Slovak Republic.
The present work describes the process of the creation and analysis of the first dataset containing processing parameters and functional properties of soft magnetic composites (SMC). All data were obtained experimentally using Fe-3% MgO system. When creating samples, parameters such as a size of MgO nanoparticles, pressing pressure, sintering temperature, time and atmosphere were varied.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Mechanical Engineering, Kerman Branch, Islamic Azad University, Kerman, Iran.
This article introduces an innovative multipurpose system that integrates a solar power plant with a coastal wind farm to generate refrigeration for refinery processes and industrial air conditioning. The system comprises multiple wind turbines, solar power plants, the Kalina cycle to provide partial energy for the absorption refrigeration cycle used in industrial air conditioning, and a compression refrigeration cycle for propane gas liquefaction. An extensive energy and exergy analysis was conducted on the proposed system, considering various thermodynamic parameters such as the solar power plant's energy output, the absorption chiller's cooling load, the electricity generated by the turbines, the wind turbines' power output, and the energy efficiency and exergy of each cycle within the system.
View Article and Find Full Text PDFNat Commun
January 2025
Guangxi Key Laboratory of Clean Pulp & Papermaking and Pollution Control, School of Light Industry and Food Engineering, Guangxi University, Nanning, 530004, PR China.
Skin-like sensors capable of detecting multiple stimuli simultaneously have great potential in cutting-edge human-machine interaction. However, realizing multimodal tactile recognition beyond human tactile perception still faces significant challenges. Here, an extreme environments-adaptive multimodal triboelectric sensor was developed, capable of detecting pressure/temperatures beyond the range of human perception.
View Article and Find Full Text PDFNat Commun
January 2025
Center for High Pressure Science and Technology Advanced Research, Beijing, 100093, China.
Due to the sulfur's atoms' propensity to form molecules and/or polymeric chains of various sizes and configuration, elemental sulfur possesses more allotropes and polymorphs than any other element at ambient conditions. This variability of the starting building blocks is partially responsible for its rich and fascinating phase diagram, with pressure and temperature changing the states of sulfur from insulating molecular rings and chains to semiconducting low- and high-density amorphous configurations to incommensurate superconducting metallic atomic phase. Here, using a fast compression technique, we demonstrate that the rapid pressurisation of liquid sulfur can effectively break the molecular ring structure, forming a glassy polymeric state of pure-chain molecules (Am-S).
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