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Activating TiO through the Phase Transition-Mediated Hydrogen Spillover to Outperform Pt for Electrocatalytic pH-Universal Hydrogen Evolution. | LitMetric

AI Article Synopsis

  • * Researchers successfully activate TiO for electrocatalytic hydrogen evolution through a process involving dual doping (with nitrogen and fluorine) that triggers a phase change from anatase to rutile.
  • * The modified TiO shows impressive hydrogen evolution rates with lower overpotentials compared to pure TiO and even surpasses the performance of expensive platinum-based catalysts, suggesting a promising alternative for cost-effective hydrogen production.

Article Abstract

Endowing conventional materials with specific functions that are hardly available is invariably of significant importance but greatly challenging. TiO is proven to be highly active for the photocatalytic hydrogen evolution while intrinsically inert for electrocatalytic hydrogen evolution reaction (HER) due to its poor electrical conductivity and unfavorable hydrogen adsorption/desorption behavior. Herein, the first activation of inert TiO for electrocatalytic HER is demonstrated by synergistically modulating the positions of d-band center and triggering hydrogen spillover through the dual doping-induced partial phase transition. The N, F co-doping-induced partial phase transition from anatase to rutile phase in TiO (AR-TiO|(N,F)) exhibits extraordinary HER performance with overpotentials of 74, 80, and 142 mV at a current density of 10 mA cm in 1.0 M KOH, 0.5 M HSO, and 1.0 M phosphate-buffered saline electrolytes, respectively, which are substantially better than pure TiO, and even superior to the benchmark Pt/C catalysts. These findings may open a new avenue for the development of low-cost alternative to noble metal catalysts for electrocatalytic hydrogen production.

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Source
http://dx.doi.org/10.1002/smll.202400783DOI Listing

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