Bottom-Up Synthesis of Twisted Porous Graphene through a Heterogeneous Scholl Reaction and Its Supercapacitor Application.

Anthracene- and pyrene-based twisted porous graphene () with an ordered pore structure has been synthesized through bottom-up solution phase synthesis from a conjugated microporous polymer () via a heterogeneous Scholl cyclization reaction. The regular-ordered pores embedded within the graphene structures were analyzed through a Raman spectrum, different morphological analyses, and theoretical studies. A significant change in surface area from to was observed, from 143 to 640 m/g, respectively. Surface area-driven capacitive properties were also observed. Twisted-structure and ordered porous graphene shows better specific capacitance compared to CMP. shows a specific capacitance of 629 F g at 1 A g, with 91% retention of capacitance after 3000 charge-discharge cycles, whereas shows a maximum specific capacitance of 200 F g was observed at 2 A g.