A straightforward and convenient approach for producing AgCN at room temperature using acetonitrile as a source has been developed, employing various iron salts. To date, there have been no prior studies documenting the synthesis of AgCN by cleaving the C-CN bond in acetonitrile with the use of iron salts. The resulting highly crystalline material was subjected to characterization through XRD and FT-IR analysis. Additionally, the same process was used for C-CN bond breaking using AgS or the formation of an AgSO composite. Consequently, this report is primarily dedicated to exploring the efficacy of different iron salts in breaking the C-CN bond in CHCN. A theoretical investigation of the proposed experimental scheme has also been performed to confer the feasibility of the reaction.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10985703 | PMC |
| http://dx.doi.org/10.1039/d4ra01790k | DOI Listing |
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