Although radio frequency (RF) technology is routinely employed for controlling high-energy pulses of electrons, corresponding technology has not been developed at beam energies below several kiloelectronvolts. In this work, we demonstrate transverse and longitudinal phase-space manipulation of low-energy electron pulses using RF fields. A millimeter-sized photoelectron gun is combined with synchronized streaking and compression cavities driven at frequencies of and , respectively. The phase-controlled acceleration and deceleration of photoelectron pulses is characterized in the energy range of -. Deflection from a transient space-charge cloud at a metal grid is used to measure a fourfold compression of electron pulses, from to pulse duration.
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http://dx.doi.org/10.1063/4.0000235 | DOI Listing |
J Phys Chem Lett
January 2025
Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir Prelog Weg 2, 8093 Zurich, Switzerland.
Relaxation-induced dipolar modulation enhancement (RIDME) is a pulse EPR experiment originally designed to determine distances between spin labels. However, RIDME has several features that make it an efficient tool in a number of "nonconventional" applications, away from the original purpose of this pulse experiment. RIDME appears to be an interesting experiment to probe longitudinal electron spin dynamics, e.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Northwest University, College of Chemistry & Materials Science, CHINA.
The encapsulation of viologen derivatives in metal-organic frameworks (MOFs) to construct host-guest materials has been widely discussed owing to their distinctive spatial arrangement and physical/chemical properties. Herein, three new photochromic MOFs (NWM-1-3) have been successfully synthesized by 1,1,2,2-Tetra(4-carboxylphenyl)ethylene (H4TCPE) ligand as well as three different viologen derivatives based on host-guest strategy. Remarkably, NWM-1-3 exhibit a notable reversible photochromism change from yellow to green under 365 nm UV irradiation.
View Article and Find Full Text PDFAdv Mater
January 2025
Max Planck Institute for Solid State Research, Heisenbergstr. 1, 70569, Stuttgart, Germany.
The rapid advancement of covalent organic frameworks (COFs) in recent years has firmly established them as a new class of molecularly precise and highly tuneable porous materials. However, compared to other porous materials, such as zeolites and metal-organic frameworks, the successful integration of hierarchical porosity into COFs remains largely unexplored. The challenge lies in identifying appropriate synthetic methods to introduce secondary pores without compromising the intrinsic structural porosity of COFs.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
Department of Chemistry, B.S. Abdur Rahman Crescent Institute of Science and Technology, Vandalur, Chennai 600 048, India.
Pharmaceutical ingredients in water have become a serious threat to living bodies and lead to assorted ecological predicaments. In this study, we have established an electrochemical probe for the simultaneous detection of synthetic pharmaceutical ingredients, including 4-nitroquinoline-N-Oxide (NQN) and ornidazole (ODZ), in both human and environmental samples. This study establishes the detection of NQN and ODZ using a screen-printed carbon electrode (SPCE) modified by highly conducting NbN incorporated with BaZrO perovskite.
View Article and Find Full Text PDFTransplant Proc
January 2025
Guangxi Medical University, Nanning, China. Electronic address:
Background: The purpose of this study was to investigate the myocardial protective effect of Xuebijing (XBJ) injection in isolated donor heart preservation based on autophagy and NLRP3 inflammatory pathway, and to provide clues for improving the quality of donor heart preservation in the clinic.
Methods: Fourteen Guangxi Bama miniature pigs were randomly divided into two groups to establish the isolated heart perfusion model of extracorporeal membrane oxygenation (ECMO): (1) normal saline group (NS group): 50 mL normal saline was added to the perfusion solution; and (2) Xuebijing injection group (XBJ group): 10 mL of XBJ was added to the perfusate. Both groups were continuously pumped with 5 mL/h for 8 hours.
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