This research investigates into the efficacy of algae and algae-bacteria symbiosis (ABS) in efficiently decolorizing Remazol Red 5B, a prevalent dye pollutant. The investigation encompasses an exploration of the biosorption isotherm and kinetics governing the dye removal process. Additionally, various machine learning models are employed to predict the efficiency of dye removal within a co-culture system. The results demonstrate that both Desmodesmus abundans and a composite of Desmodesmus abundans and Rhodococcus pyridinivorans exhibit significant dye removal percentages of 75 ± 1% and 78 ± 1%, respectively, after 40 min. The biosorption isotherm analysis reveals a significant interaction between the adsorbate and the biosorbent, and it indicates that the Temkin model best matches the experimental data. Moreover, the Langmuir model indicates a relatively high biosorption capacity, further highlighting the potential of the algae-bacteria composite as an efficient adsorbent. Decision Trees, Random Forest, Support Vector Regression, and Artificial Neural Networks are evaluated for predicting dye removal efficiency. The Random Forest model emerges as the most accurate, exhibiting an R value of 0.98, while Support Vector Regression and Artificial Neural Networks also demonstrate robust predictive capabilities. This study contributes to the advancement of sustainable dye removal strategies and encourages future exploration of hybrid approaches to further enhance predictive accuracy and efficiency in wastewater treatment processes.
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http://dx.doi.org/10.1016/j.chemosphere.2024.141791 | DOI Listing |
ACS Omega
December 2024
Department of Nanoscience and Nanoengineering, Atatürk University, Erzurum 25030, Turkiye.
In this paper, we present a facile yet effective method for the fabrication of core-shell nanoparticles (NPs) of magnetite (FeO) and polydopamine (FeO@PDA) and their decoration with a tunable amount of gold NPs (AuNPs). For this, FeO NPs were fabricated through the polyol method and AuNPs were deposited onto FeO@PDA via anchoring of as-prepared citrate-stabilized AuNPs or reduction of Au ions. PDA with its numerous catechol groups enabled the decoration of AuNPs in a well-controlled manner.
View Article and Find Full Text PDFSci Rep
January 2025
Department of Chemistry, College of Basic Sciences, Yadegar-E-Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, Iran.
This study presents the development and characterization of manganese ferrite (MnFeO)-based nanocomposites with graphite oxide (GO) and chitosan (CS) for efficient dye removal from textile wastewater and aqueous solution. Comprehensive characterization was performed using FT-IR, Raman, XRD, BET, SEM, DRS and Zeta potential techniques. XRD analysis confirmed the cubic spinel structure of MnFeO, with characteristic peaks at 2θ = 32, 35, 48, 53, 62, and 64°.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
Amity Institute of Pharmacy, Amity University Haryana, Amity Education Valley, Panchgaon, Manesar, Gurugram, Haryana 122413, India. Electronic address:
Climate change, the overconsumption of fossil fuels, and rapid population and economic growth have collectively driven a growing emphasis on environmental sustainability and the need for effective resource management. Chemicals or materials not currently regulated are known as contaminants of emergent concern (CECs). Nevertheless, wastewater is thought to be its main source, and worries about its probable presence in the environment are growing due to its potential damage to human and environmental health.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
College of Resources and Environmental Engineering, Wuhan University of Science and Technology, Wuhan 430081, China.
Chitosan, as a natural and environmentally friendly material, has attracted significant attention in the field of water treatment. In this study, a Chitosan/poly (dimethyl diallyl ammonium chloride-co-acrylamide) composite hydrogel (CPDA hydrogel) featuring a semi-interpenetrating network structure was synthesized via free radical copolymerization for the removal of the anionic dye Congo Red (CR) from wastewater. SEM-EDS, FTIR, XPS, TG, Zeta potential, and mercury intrusion porosimetry (MIP) were employed to analyze the physical and chemical changes in the hydrogel before and after adsorption.
View Article and Find Full Text PDFInt J Biol Macromol
January 2025
School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus, 14300 Nibong Tebal, Penang, Malaysia.
The polyvinyl alcohol/chitosan (PVA/CS) thin film membrane was modified using a deep eutectic solvent (DES) to enhance its adsorption capability and mechanical strength for the removal of brilliant green (BG) dye. Batch adsorption experiments, machine learning (ML) modeling, and density functional theory (DFT) analyses were performed to evaluate the adsorption of BG using PVA/CS and DES-modified PVA/CS (DES/PVA/CS) membranes. Incorporating DES (5 wt%) into the PVA/CS membrane increased its elongation at break from 8.
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