SiN bioceramics were fabricated using GPS and SPS method with MgO-REO (RE = La, Nd, Gd, Ho and Lu) sintering additives. The effect of sintering methods and sintering additives on the grain growth, mechanical, antimicrobial properties and color of SiN bioceramics were studied. Samples sintered with GPS are composed of β-SiN and samples sintered with SPS are composed of α-SiN and β-SiN. The growth of β-SiN grains in samples sintered with GPS are more adequate. Samples sintered with GPS exhibit a S. aureus inactivation rate up to 98% and a bright color appearance with a hardness of about 13 GPa and a fracture toughness up to 7.5 MPa m, suitable for dental implants. And samples sintered with SPS exhibit a hardness of about 17 GPa and a fracture toughness about 6 MPa m.
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http://dx.doi.org/10.1016/j.jmbbm.2024.106529 | DOI Listing |
ACS Appl Mater Interfaces
January 2025
Faculty of Engineering and Natural Sciences, Sabanci University, Istanbul 34956, Turkey.
Cold isostatic pressing, gel casting, and protein coagulation are the most common techniques to produce green bodies prior to computer numerical control (CNC)-based machining for the near-net-scale shaping of ceramics. These methods typically involve various additives and entail several steps to create a green body that is capable of withstanding machining forces. Here, utilizing a single additive, we first introduced a facile benchtop method to generate self-standing, malleable doughs of alumina in under 2 min.
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December 2024
Department of Applied Science and Technology (DISAT), Politecnico di Torino, Corso Duca Degli Abruzzi 24, 10129 Torino, Italy.
The paper highlights the realization of 3D-printed parts with complex geometries, such as chess-like pieces, using polyamide 12 (PA12) as polymeric powder via selective laser sintering (SLS). The research activity focuses on the study of the powder printability, the optimization of the printing parameters, and the tomographic evaluation of the printed objects. Morphological analyses were carried out to study the PA12 powder microstructure considering that SLS required specific particle size distribution and shape, able to guarantee a good flowability necessary to take part in a sintering process.
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December 2024
Department of Prosthodontics, Medical University of Warsaw, 02-097 Warsaw, Poland.
Incorporating nanoparticles into denture materials shows promise for the prevention of denture-associated fungal infections. This study investigates the antifungal properties of acrylic modified with microwave-sintered ZnO-Ag nanoparticles. ZnO-Ag nanoparticles (1% and 2.
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December 2024
Department of Engineering "Enzo Ferrari", University of Modena and Reggio Emilia, Via P. Vivarelli 10, 41125 Modena, Italy.
The development of new bioactive glasses (BGs) with enhanced bioactivity and improved resistance to crystallization is crucial for overcoming the main challenges faced by commercial BGs. Most shaping processes require thermal treatments, which can induce partial crystallization, negatively impacting the biological and mechanical properties of the final product. In this study, we present a novel bioactive glass composition, S53P4_MSK, produced by a melt-quench route.
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December 2024
Key Laboratory of Green Chemical Process of Ministry of Education, School of Chemistry and Environmental Engineering, Wuhan Institute of Technology, Wuhan 430205, China.
Polydispersed Ag species-modified TiO samples with abundant oxygen vacancies were successfully prepared through the calcination of atomically precise Ag nanocluster-loaded TiO at an optimal temperature under a nitrogen atmosphere. The ligands of the Ag nanoclusters are removed by extracting lattice oxygen from TiO during the calcination, leading to the formation of CO, SO, and HO vapor. This process simultaneously induces Ag species sintering on the surface of TiO.
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