Synthesis of fully bio-based poly (3-hydroxybutyrate)-oligo-2-ethyl oxazoline conjugates.

Front Chem

Departments of Chemistry/Nano Technology Engineering, Zonguldak Bülent Ecevit University, Zonguldak, Türkiye.

Published: March 2024

This work refers to the synthesis and characterization of poly (3-hydroxybutyrate)-b-oligo (2-ethyl oxazoline) (oligoEtOx). Cationic ring-opening polymerization of 2-ethyl oxazoline yielded poly (2-ethyl oxazoline) (oligoEtOx) with a hydroxyl end. Carboxylic acid-terminated PHB was reacted with oligoEtOx via dicyclohexylcarbodiimide chemistry to obtain PHB-b-oligoEtOx conjugates. The obtained PHB-b-oligoEtOx conjugates were successfully characterized by H- and C NMR, FTIR, DSC, and size exclusion chromatography. PHB-b-oligoEtOx conjugates can be promising biologic active materials.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10972867PMC
http://dx.doi.org/10.3389/fchem.2024.1367451DOI Listing

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