(KNa)NbO (KNN)-based ceramics have been extensively investigated as replacements for Pb(Zr, Ti)O-based ceramics. KNN-based ceramics exhibit an orthorhombic structure at room temperature and a rhombohedral-orthorhombic (R-O) phase transition temperature (), orthorhombic-tetragonal (O-T) phase transition temperature (), and Curie temperature of -110, 190, and 420 °C, respectively. Forming KNN-based ceramics with a multistructure that can assist in domain rotation is one technique for enhancing their piezoelectric properties. This review investigates and introduces KNN-based ceramics with various multistructures. A reactive-templated grain growth method that aligns the grains of piezoceramics in a specific orientation is another approach for improving the piezoelectric properties of KNN-modified ceramics. The piezoelectric properties of the [001]-textured KNN-based ceramics are improved because their microstructures are similar to those of the [001]-oriented single crystals. The improvement in the piezoelectric properties after [001] texturing is largely influenced by the crystal structure of the textured ceramics. In this review, [001]-textured KNN-based ceramics with different crystal structures are investigated and systematically summarized.
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http://dx.doi.org/10.3390/mi15030325 | DOI Listing |
Small
December 2024
College of Materials Science and Engineering, Sichuan University, Chengdu, 610064, China.
Piezoelectric materials are increasingly used in portable smart electronics and Internet of Things sensors. Among them, piezoelectric macro fiber composites (MFCs) have attracted much attention due to their architectural simplicity, scalability, and high-power density. However, most MFCs currently use toxic lead-based piezoelectric materials, hindering their applications for bio-friendly intelligent electronics.
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December 2024
State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing, 100084, China.
Nat Commun
October 2024
School of Materials Science and Engineering, Tongji University, Shanghai, China.
Molecules
September 2024
School of Materials Science and Engineering, Liaocheng University, Liaocheng 252059, China.
ACS Appl Mater Interfaces
October 2024
College of Materials Science and Engineering, Sichuan University, 610064 Chengdu, China.
The splendid energy storage performances with eminent stability of dielectric ceramics utilized in pulsed power devices have been paid more attention by researchers. This scheme can be basically realized through introducing Li, Bi(MgTa)O, NaNbO, and LiF into KNN-based ceramics. Under the breakdown strength (BDS) of 460 kV/cm, an outstanding energy storage density () of 6.
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