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Article Abstract
Photoinduced cascade of two 6π-electron six- and five-center electrocyclizations in aromatic azido imines is oxidatively controlled to yield complex fused benzimidazoles or indazoles. Formation of benzimidazoles occurs via an unprecedented carbon-to-nitrogen -iminoaryl 1,2-shift.
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| http://dx.doi.org/10.1021/acs.orglett.4c00361 | DOI Listing |
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