The utilization of adhesive compounds in bonding lightweight and high-performance composite structures, including carbon fiber reinforced polymer (CFRP) composites, has garnered significant attention from researchers. This study presents the novel application of AlO coated with TiO as a thermal protective layer for CFRP substrate. Initially, the CFRP substrate underwent a protective treatment involving the application of AlO as a middle coat, followed by a further protective layer consisting of TiO as a top coat. The deposition of TiO onto an AlO-based thermal barrier coating (TBC) was carried out utilizing the flame spray method. The use of a TiO coating as a top coat was employed to enhance protection and heat dispersion across the middle coat and substrate. In order to achieve sufficient adhesion between the CFRP substrate, an intermediate coat consisting of AlO with a NaSiO binder, the impact of varying nozzle distances on adhesion strength and pull-off test outcomes was investigated, with a nozzle distance of 180 mm yielding the highest adhesion strength. The thermal stability of a CFRP substrate was enhanced through the deposition of a layer of TiO on AlO. The surface and cross-sectional morphologies of the composite were analyzed using a Scanning Electron Microscope (SEM). It was observed that the presence of a TBC on the composite surface effectively reduced the amount of heat that was transferred to the composite material. In order to assess the effectiveness of TBC on CFRP substrates, a series of experiments involving thermal torch and conductivity tests were undertaken. The interaction between the top and middle coats of a composite material results in enhanced mechanical properties, hence improving its thermal insulation capabilities. The artificially produced TBC coatings have the potential to function as adhesive materials, ensuring the sustained high performance of CFRP substrates.
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http://dx.doi.org/10.1039/d3ra08518j | DOI Listing |
J Am Chem Soc
November 2024
Department of Chemistry, Donald P. and Katherine B. Loker Hydrocarbon Institute, and Wrigley Institute for Environment and Sustainability, University of Southern California, Los Angeles, California 90089, United States.
Carbon fiber reinforced polymers (CFRPs, or composites) are increasingly replacing traditional manufacturing materials used in the automobile, aerospace, and energy sectors. With this shift, it is vital to develop end-of-life processes for CFRPs that retain the value of both the carbon fibers and the polymer matrix. Here we demonstrate a strategy to upcycle pre- and postconsumer polystyrene-containing CFRPs, cross-linked with unsaturated polyesters or vinyl esters, to benzoic acid.
View Article and Find Full Text PDFSensors (Basel)
July 2024
Department of Materials Science and Engineering, University of Sheffield, Sheffield S1 3JD, UK.
Inkjet printing of magnetic materials has increased in recent years, as it has the potential to improve research in smart, functional materials. Magnetostriction is an inherent property of magnetic materials which allows strain or magnetic fields to be detected. This makes it very attractive for sensors in the area of structural health monitoring by detecting internal strains in carbon fibre-reinforced polymer (CFRP) composite.
View Article and Find Full Text PDFAdv Sci (Weinh)
July 2024
State Key Laboratory of Materials Processing and Die and Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China.
Structural materials such as ceramics, metals, and carbon fiber-reinforced plastics (CFRP) are frequently threatened by large compressive and impact forces. Energy absorption layers, i.e.
View Article and Find Full Text PDFMaterials (Basel)
March 2024
Department of Mechanical Engineering, University of South Alabama, Mobile, AL 36688, USA.
Low fiber-direction compressive strength is a well-recognized weakness of carbon fiber-reinforced polymer (CFRP) composites. When a CFRP is produced using 3D printing, the compressive strength is further degraded. To solve this issue, in this paper, a novel magnetic compaction force-assisted additive manufacturing (MCFA-AM) method is used to print CFRP laminates reinforced with carbon nanofiber (CNF) z-threads (i.
View Article and Find Full Text PDFMaterials (Basel)
February 2024
Department of Civil and Environmental Engineering, Center for Composite Materials, University of Delaware, Newark, DE 19716, USA.
Externally bonded wet-layup carbon fiber-reinforced polymer (CFRP) strengthening systems are extensively used in concrete structures but have not found widespread use in deficient steel structures. To address the challenges of the adhesive bonding of wet-layup CFRP to steel substrates, this study investigated the effect of core-shell rubber (CSR) nanoparticles on the curing kinetics, glass transition temperature (Tg) and mechanical properties of ambient-cured epoxy/CSR blends. The effects of silane coupling agent and CSR on the adhesive bond properties of CFRP/steel joints were also investigated.
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