Eur J Inorg Chem
Institut für Allgemeine, Anorganische und Theoretische Chemie Universität Innsbruck Innrain 80-82 6020 Innsbruck Austria.
Published: September 2023
New clathrochelate complexes of manganese, iron and cobalt containing peripheral organometallic manganese moieties cymantrene or tromancenium were synthesized via self-assembly from di/tri-topic dioximes, metal templates and cymantrene/tromancenium boronic acid pinacol esters. These air-stable, highly colored, oligometallic complexes are composed of various combinations of MnFeMn, MnCoMn, MnMnMnMn and MnCoCoMn metal assemblies with corresponding complicated magnetic and electrochemical properties. Full spectroscopic and structural characterization by H/B/C NMR, HRMS, IR, UV-vis, single crystal XRD and CV (cyclic voltammetry) is provided. Tetrametallic complexes containing tromanceniumyl substituents with two Co or Mn central metals exhibit promising anticancer properties against different tumor cell lines.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10947045 | PMC |
http://dx.doi.org/10.1002/ejic.202300368 | DOI Listing |
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