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CO storage as hydrates in porous media is a promising method for storing carbon dioxide (CO). However, the sluggish formation kinetics of hydrates urge the need to focus on the use of additives (promoters) to accelerate hydrate kinetics. This study investigates the effect of amino acid solutions in brine on CO hydrate formation and dissociation kinetics in quartz sand particles QS-2 (0.6-0.8 mm) with 38% porosity. The amino acids l-methionine (l-meth), l-isoleucine (l-iso), and l-threonine (l-threo) were studied at 0.2 wt% using an autoclave hydrate reactor at 4 MPa and 274.15 K in the presence and absence of salt (3.3 wt% NaCl) in 100% water saturation. The hydrate dissociation kinetics was studied at a temperature of 277.15 K. These conditions represent the normal seabed temperature range in Malaysia and hence were used for testing CO hydrate formation and dissociation kinetics in quartz sand in this study. Further, CO hydrate formation and dissociation experiments were conducted with sodium dodecyl sulphate (SDS) and brine systems as standards for comparison. The findings reveal the best kinetics for l-meth exhibiting the highest CO hydrate storage capacity. l-meth recorded a gas-to-hydrate conversion ratio of about 93% at 0.2 wt% in quartz sand with brine. Moreover, l-meth exhibited the lowest hydrate dissociation rate compared to l-iso and l-threo systems, thereby enhancing CO hydrate stability in quartz sand. Comparatively, l-meth enhanced the storage capacity by 36% and reduced the induction time by more than 50% compared to conventional promoter SDS in quartz sand with brine, suggesting it to be favorable for CO storage applications. CO hydrate nucleation time was predicted in quartz sand with and without the best-studied amino acid l-meth system with high prediction accuracy and an absolute average deviation of 2.4 hours. The findings of this study substantiate the influence of amino acids in promoting the storage capacity of CO in sediments as hydrates.
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http://dx.doi.org/10.1039/d4ra00330f | DOI Listing |
Materials (Basel)
December 2024
College of Civil Engineering, Hunan University of Science and Technology, Xiangtan 411201, China.
The study of dredged fill in Guangdong (GD), China, is of great significance for reclamation projects. Currently, there are relatively few studies on dredged fill in Guangdong, and there are many differences in the engineering characteristics of dredged fill foundations formed through land reclamation and natural foundations. In order to have a more comprehensive understanding of the physico-mechanical properties of blowing fill in the coastal area of GD and to understand the effect of its long-term creep row on the long-term settlement and deformation of buildings, the material properties, microstructure, elemental composition, triaxial shear properties, and triaxial creep properties of dredged fill in Guangdong were studied and analyzed through indoor geotechnical tests, scanning electron microscopy (SEM), X-ray diffraction (XRD), and conventional triaxial shear tests and triaxial creep tests.
View Article and Find Full Text PDFMaterials (Basel)
December 2024
Faculty of Materials, Metallurgy and Recycling, Technical University of Kosice, Letna 1/9, 042 00 Kosice, Slovakia.
The ongoing sustainable reduction in natural resources is prompting companies to look for materials to reuse that were previously classified as waste. Uses are sought for them either in their existing area of use or in other areas of the economy. In many cases, this is difficult.
View Article and Find Full Text PDFMaterials (Basel)
November 2024
School of Safety Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
The roles of dielectric materials in adjusting the electromagnetic wave (EMW) absorption performance of an EMW absorber are as crucial as the EMW absorbents. The commonly used cement-based materials, such as mortar, are typical composites of multiple dielectric materials, such as quartz sand and air in the pores. This study investigates the EMW-absorption performances within the frequency range of 2 GHz to 18 GHz of cement paste and mortar samples with different sand-to-cement ratios (S/C), water-to-cement ratios (W/C), and thicknesses.
View Article and Find Full Text PDFPolymers (Basel)
November 2024
Faculty of Architecture, Civil and Transportation Engineering, Beijing University of Technology, Beijing 100124, China.
The study of the co-transport of Cr(VI) and microplastics (MPs) in porous media is important for predicting migration behavior and for achieving pollution removal in natural soils and groundwater. In this work, the effect of MPs on Cr(VI) migration in saturated porous media was investigated at different ionic strengths (ISs) and pHs. The results showed that pH 7 and low IS (5 mM), respectively, promoted the movement of Cr(VI), which was further promoted by the presence of MPs.
View Article and Find Full Text PDFChemosphere
December 2024
College of Environment and Ecology, Chongqing University, Chongqing, PR China. Electronic address:
The sulfur redox cycling, mainly involving sulfide oxidation and sulfate reduction, remains a crucial factor that regulates the treatment performance of constructed wetlands (CWs). However, anoxic environments normally prevail in the CW systems, harboring vast reduced sulfur and sulfur minerals, where the occurrence and mechanism of anoxic sulfide oxidation remain unknown. In this study, CW microcosms filled with quartz sand (Qtz) and pyrite (Pyt) were established to investigate the anoxic sulfur oxidation under the bioelectrochemical manipulations.
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