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Ionic Liquid-Functionalized Defective MOFs for Membrane-Based CO Separation: A Dual Optimization Approach for Interface and Transport.
ACS Appl Mater Interfaces
January 2025
School of Chemical Engineering, Zhengzhou University, Zhengzhou 450001, P. R. China.
Defective MOFs have been identified as promising candidates for efficient membrane-based separation applications. However, the utilization of defective MOFs in membrane gas separation is still in its infancy due primarily to the inefficient molecular differentiation induced by structural defects. Herein, we report a strategic combination of ionic liquid (IL) and defective UiO-66-NH MOF to ameliorate the CO/N selectivity within the highly permeable PIM-1 polymer.
View Article and Find Full Text PDFAn integrated approach to uncertainty and global sensitivity analysis in penstock structural modeling.
Heliyon
January 2025
Department of Mechanical Engineering, Mohammadia School of Engineering, Avenue Ibn Sina B.P 765, Agdal, Rabat, 10090, Morocco.
Enhanced penstock structural models significantly advance hydropower engineering, yet their increasing complexity introduces challenges. As model interactions intensify, predictability and comprehensibility decrease, complicating the evaluation of model accuracy and alignment with operational performance metrics and safety standards. This issue is particularly pronounced in dynamic modeling, where knowledge gaps hinder straightforward validation via observational data.
View Article and Find Full Text PDFWhat happened next? A survey of review clients evaluating impacts of rapid reviews.
J Clin Epidemiol
January 2025
National Collaborating Centre for Methods and Tools,175 Longwood Rd. S., Suite 210A, Hamilton, ON, L8P 0A1; School of Nursing, McMaster University, Health Sciences Centre, 2J20, 1280 Main St W, Hamilton, ON, L8S 4K1, Canada.
Introduction: End-user evaluation of the impact of evidence syntheses is critical to demonstrating value. This study presents results of a survey evaluating the impact of rapid reviews undertaken by two teams based in Melbourne, Australia and Hamilton, Canada.
Methods: Clients were invited to participate in a short, written survey following delivery of a rapid review.
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Sci Data
January 2025
The Department of Biomedical and Health Informatics, The Children's Hospital of Philadelphia, Philadelphia, PA, USA.
The Homo sapiens Chromosomal Location Ontology (HSCLO) is designed to facilitate the integration of human genomic features into biomedical knowledge graphs from releases GRCh37 and GRCh38 at multiple resolutions. HSCLO comprises two distinct versions, HSCLO37 and HSCLO38, each tailored to its respective human genome release. This ontology supports the efficient integration and analysis of human genomic data across scales ranging from entire chromosomes to individual base pairs, thereby enhancing data retrieval and interoperability within large-scale biomedical datasets.
View Article and Find Full Text PDFA Multifaceted Luminescent Europium(III) Probe for the Discrimination of Nucleoside Phosphates and Detection of Organophosphate Nerve Agents.
Inorg Chem
January 2025
Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh 208016, India.
The nucleotides play multiple fundamental roles that are essential in biochemical enzymatic reactions and signaling pathways. Many diseases are closely associated with their dysregulation. Therefore, reliable and sensitive optical probes to discriminate various nucleotides are essential in biochemistry, drug discovery, and disease diagnosis.
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