Strain solitons are quasi-dislocations that form in van der Waals materials to relieve the energy associated with lattice or rotational mismatch. Novel electronic properties of strain solitons were predicted and observed. To date, strain solitons have been observed only in exfoliated crystals or mechanically strained crystals. The lack of a scalable approach toward the generation of strain solitons poses a significant challenge in the study of and use of their properties. Here, we report the formation of strain solitons with epitaxial growth of bismuth on InSb(111)B by molecular beam epitaxy. The morphology of the strain solitons for films of varying thickness is characterized with scanning tunneling microscopy, and the local strain state is determined from atomic resolution images. Bending in the solitons is attributed to interactions with the interface, and large angle bending is associated with edge dislocations. Our results enable the scalable generation of strain solitons.
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http://dx.doi.org/10.1021/acs.nanolett.4c00382 | DOI Listing |
Nano Lett
January 2025
National Laboratory of Solid-State Microstructures, School of Electronic Science and Engineering and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing 210093, Jiangsu, China.
Strain solitons have been widely observed in van der Waals materials and their heterostructures. They can manifest as one-dimensional (1D) wires and quasi-two-dimensional (2D) networks. However, their coexistence within the same region has rarely been observed, and their interplay remains unexplored.
View Article and Find Full Text PDFSci Adv
December 2024
College of Physics, Sichuan University, Chengdu, Sichuan 610064, China.
Polaritons in two-dimensional (2D) materials provide unique opportunities for controlling light at nanoscales. Tailoring these polaritons via gradient polaritonic surfaces with space-variant response can enable versatile light-matter interaction platforms with advanced functionalities. However, experimental progress has been hampered by the optical losses and poor light confinement of conventionally used artificial nanostructures.
View Article and Find Full Text PDFSmall
December 2024
Materials Research Centre, Indian Institute of Science, Bangalore, Karnataka, 560012, India.
Topological polar soliton such as skyrmions, merons, vortices, flux closures represent topologically nontrivial structures with their stability governed by specific boundary conditions. These polar solitons can be utilized in enhancing memory density and reducing energy consumption in nanoelectronic devices. Flux closure domains exhibit high density and thermal stability, with a strain gradient as large as ≈10 m at the core, which is tunable by adjusting the materials thickness, periodicity.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
December 2024
Tandon School of Engineering, Chemical and Biomolecular Engineering, New York University, Brooklyn, NY 11201.
Emergent electronic phenomena, from superconductivity to ferroelectricity, magnetism, and correlated many-body band gaps, have been observed in domains created by stacking and twisting atomic layers of Van der Waals materials. In graphene, emergent properties have been observed in ABC stacking domains obtained by exfoliation followed by expert mechanical twisting and alignment with the desired orientation, a process very challenging and nonscalable. Here, conductive atomic force microscopy shows in untwisted epitaxial graphene grown on SiC the surprising presence of striped domains with dissimilar conductance, a contrast that demonstrates the presence of ABA and ABC domains since it matches exactly the conductivity difference observed in ABA/ABC domains in twisted exfoliated graphene and calculated by density functional theory.
View Article and Find Full Text PDFAdv Sci (Weinh)
October 2024
School of Information Science and Engineering, and Key Laboratory of Laser and Infrared System of Ministry of Education, Shandong University, Qingdao, 266237, China.
This study enhances the ultrafast photonics application of tin selenide (SnSe) nanoflakes via copper (Cu) functionalization to overcome challenges such as low conductivity and weak near-infrared (NIR) absorption. Cu functionalization enhances concentration, induces strain, and reduces the bandgap through Sn substitution and Sn vacancy filling with Cu ions. Demonstrated by density functional theory calculations and experimental analyses, Cu-functionalized SnSe exhibits improved NIR optical absorption and superior third-order nonlinear optical properties.
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