A uranium(III) silylate complex [K(DME)][UI{(Si(SiMe)SiMe)O}] (1) was stabilized by the addition of 18-crown-6, forming [K(18-crown-6)][UI{(Si(SiMe)SiMe)O}] (1-crown). Crystallization under multiple conditions resulted in three distinct molecular structures. Compound 1-crown was further characterized in the solution state H, C, and Si NMR spectroscopy, and electronic absorption spectroscopy.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d4cc00655k | DOI Listing |
Publication Analysis
Top Keywords
solution solid-state
4
solid-state characterization
4
characterization rare
4
rare silyluraniumiii
4
silyluraniumiii complexes
4
complexes uraniumiii
4
uraniumiii silylate
4
silylate complex
4
complex [kdme][ui{sisimesimeo}]
4
[kdme][ui{sisimesimeo}] stabilized
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!