In recent years, the application of machine learning for virtual sensing has revolutionized the monitoring and management of information. In particular, electrochemical sensors generate large amounts of data, allowing the application of complex machine learning/AI models able to (1) reproduce the measured data and (2) predict and manage faults in the measuring sensor. In this work, data-driven models based on an autoregressive model and an artificial neural network have been identified and used to (i) evaluate sensor redundancy and (ii) predict and manage faults in the context of electrochemical sensors for the measurement of ethanol. The approach shows encouraging results in terms of both performance and sensitivity analyses, allowing for the reconstruction of the values measured by two sensors in a series of six sensors with different dopant levels and to reproduce their values after a fault.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10933999 | PMC |
http://dx.doi.org/10.3390/s24051396 | DOI Listing |
Braz J Microbiol
January 2025
Centro de Ciências, Universidade Estadual do Ceará, CCT, Fortaleza, Brazil.
Carbon dots in biosensing have advanced significantly, adding improvements to different detection techniques. In this study, an amperometric immunosensor for Salmonella Thyphimurium was designed using antibodies labeled with carbon dots (Cdots) from pequi almond (Caryocar brasiliensis). Cdots were synthesized by pyrolysis and characterized by FTIR, UV/fluorescence, electrochemistry, zeta potential, and transmission electron microscopy (TEM).
View Article and Find Full Text PDFMikrochim Acta
January 2025
Jiangxi Provincial Key Laboratory of Improved Variety Breeding and Efficient Utilization of Native Tree Species 2024SSY04093, College of Forestry, East China Woody Fragrance and Flavor Engineering Research Center of NF&GA, Jiangxi Agricultural University, Nanchang, 330045, People's Republic of China.
A convenient method is proposed using a heat-treatable volatile template to prepare hierarchical porous biochar (HPB). Litsea cubeba leaves and ZIF-8 served as carbon source and volatile hard template, respectively. The good compatibility between ZIF-8 and biomass facilitated their uniform dispersion, and the thermal decomposition of ZIF-8 created abundant pores in the HPB.
View Article and Find Full Text PDFJ Phys Chem Lett
January 2025
Department of Chemistry and Biochemistry, The University of Alabama, Tuscaloosa, Alabama 35487, United States.
We report a Tuning Fork Scanning Electrochemical Cell Microscopy (TF-SECCM) technique for providing morphological and electrochemical information on single redox-active entities. This new operation configuration of SECCM utilizes an electrolyte-filled nanopipette tip mounted onto a tuning fork force sensor to obtain a precise tip-sample distance control and surface morphological mapping capabilities. Redox activities of regions of interest (ROIs) can be investigated by scanning electrode potential by moving the nanopipette to any target regions while maintaining the constant force engagement of the tip with the sample.
View Article and Find Full Text PDFBiotechnol Rep (Amst)
March 2025
Department of Biology, University of York, Wentworth Way, York, YO10 5DD, UK.
Unlabelled: Ongoing research in biosensor technologies has led to advanced functional materials for healthcare diagnostics, and bacteriophages (phages), demonstrating exceptional utility due to their high specificity, accuracy, rapid, label-free, and wireless detection capabilities with minimal false-positive results. Phage-based-pathogen-detecting biosensors (PBPDBs) include surface plasmon resonance (SPR) biosensors, magnetoelastic (ME), electrochemical, and quartz crystal microbalance (QCM) biosensors. Commonly used substrates for PBPDBs are gold, silicon, glass, carbon-based materials, magnetic particles, and quantum dots.
View Article and Find Full Text PDFMikrochim Acta
January 2025
Department of Chemistry, Indian Institute of Technology Palakkad, Palakkad, Kerala, 678557, India.
Compared with previous decades, healthcare has emerged as a key global concern in light of the recurrent outbreak of pandemics. The initial stage in the provision of healthcare involves the process of diagnosis. Countries worldwide advocate for healthcare research due to its efficacy and capacity to assist diverse populations.
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