Surface Composites Synthesized through the Incorporation of Atomic Layer Deposited AlO into Nanoporous Tungsten.

The incorporation of energetic helium gaseous species into materials such as tungsten (W) imparts intrinsic surface fragility, yielding tungsten. To enhance the robustness of the surface layers, aluminum oxide (AlO) was deposited by atomic layer deposition into the W. The conformally deposited ceramic yields a new class of surface composites. Structural characterization of the W-AlO composites through nanoindentation testing indicated enhanced indentation modulus () and hardness () and was modeled through various rules of mixtures approaches. The distribution of AlO in W was explored and a systematic study of the extent of incorporation of the AlO into the W was carried out. The synthesized composites may be utilized for improved structural characteristics, e.g., in reducing crack initiation and fracture.