Bi-functional materials provide an opportunity for the development of high-performance devices. Up till now, bi-functional performance of NiCoO@SnSnanosheets is rarely investigated. In this work, NiCoO@SnSnanosheets were synthesized on carbon cloth by utilizing a simple hydrothermal technique. The developed electrode (NiCoO@SnS/CC) was investigated for the detection of L-Cysteine and supercapacitors applications. As a non-enzymatic sensor, the electrode proved to be highly sensitive for the detection of L-cysteine. The electrode exhibits a reproducible sensitivity of 4645.82A mMcmin a wide linear range from 0.5 to 5 mM with a low limit of detection (0.005M). Moreover, the electrode shows an excellent selectivity and long-time stability. The high specific surface area, enhanced kinetics, good synergy and distinct architecture of NiCoO@SnSnanosheets produce a large number of active sites with substantial energy storage potential. As a supercapacitor, the electrode exhibits improve capacitance of 655.7 F gat a current density of 2 A gas compare to NiCoO/CC (560 F g). Moreover, the electrode achieves 95.3% of its preliminary capacitance after 10 000 cycles at 2 A g. Our results show that NiCoO@SnS/CC nanosheets possess binary features could be attractive electrode material for the development of non-enzymatic biosensors as well as supercapacitors.
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http://dx.doi.org/10.1088/1361-6528/ad3219 | DOI Listing |
Inorg Chem
January 2025
Industrial Research Institute of Nonwovens & Technical Textiles, Shandong Engineering Research Center for Specialty Nonwoven Materials, College of Textiles & Clothing, Qingdao University, Qingdao, Shandong 266071, P. R. China.
Promoting the rate of the oxygen reduction reaction (ORR) is critical for boosting the overall energy efficiency of the flexible zinc-air batteries (FZABs). Inspired by nature, we designed "branch-leaf" like hierarchical porous carbon nanofibers with ultralow loadings of Ir nanoparticles (NPs) derived from covalent-organic framework/metal-organic framework (COF/MOF) core-shell hybrids. The as-obtained Ir/FeZn-hierarchical porous carbon nanofibers (HPCNFs) showcase enhanced ORR performance, and the ultralow Ir loading reduces the cost while maintaining catalytic capacity.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
College of Energy, Soochow Institute for Energy and Materials Innovations, Soochow University, Suzhou 215006 China. Electronic address:
Lithium (Li) metal anodes hold great promise for next-generation secondary batteries with high energy density. Unfortunately, several problems such as Li dendrite growth, low Coulombic efficiency and poor cycle life hinder the commercialization of Li metal anodes. Herein, we design a highly lithiophilic carbon cloth host modified with Sn-doped zinc oxide (ZnO) (ZnSn-CC) directly derived from a bimetallic ZnSn metal-organic framework (ZnSn-MOF), which boosts uniform Li plating/stripping during charge-discharge and effectively protects the Li metal anode.
View Article and Find Full Text PDFInorg Chem
January 2025
Jiangxi Province Key Laboratory of Functional Organic Polymer, School of Chemistry and Materials Science, East China University of Technology, Nanchang 330013 Jiangxi, P. R. China.
The platelike nickel-terephthalate-type metal-organic framework nanoarrays (Ni-BDC NAs) on carbon cloth are obtained by employing agaric-like Ni(OH) NAs as sacrificial templates. The microenvironment of Ni-BDC NAs is modulated by various neighboring functional groups (-NH, -NO, and -Br) on the carboxylate ligand, exerting minimal destructive effects on the structure and morphology of Ni-BDC NAs. The electrochemical oxygen evolution reaction (OER) of Ni-BDC-NH NAs, Ni-BDC-NO NAs, and Ni-BDC-Br NAs exhibited a significant enhancement compared to that of Ni-BDC NAs alone, as evidenced by both experimental and theoretical assessments.
View Article and Find Full Text PDFSmall
January 2025
Department of Chemistry, Indian Institute of Technology-Guwahati, Guwahati, Assam, 781039, India.
The design of electrically conductive textiles appears to be a promising approach to combat the existing challenge of deaths caused by severe cold climates around the globe. However, reports on the scalable fabrication of tolerant conductive textiles maintaining a low electrical resistance with an ability for unperturbed and prolonged performance are scarce. Here, a breathable and wrappable water-repellent conductive textile (water-repellent CT) with electrothermal and photothermal conversion abilities at low external voltage and in weak solar light is introduced, respectively.
View Article and Find Full Text PDFAdv Mater
January 2025
College of Textiles, Donghua University, Shanghai, 201620, China.
Fiber-based artificial muscles are soft actuators used to mimic the movement of human muscles. However, using high modulus oxide ceramics to fabricate artificial muscles with high energy and power is a challenge as they are prone to brittle fracture during torsion. Here, a ceramic metallization strategy is reported that solves the problem of low torsion and low ductility of alumina (AlO) ceramics by chemical plating a thin copper layer on alumina filaments.
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