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Synthesis, characterization, and crystal structure of 2-(2-azido-phen-yl)-3-oxo-3-indole 1-oxide. | LitMetric

Synthesis, characterization, and crystal structure of 2-(2-azido-phen-yl)-3-oxo-3-indole 1-oxide.

Acta Crystallogr E Crystallogr Commun

Organic Chemistry Division, CSIR-National Chemical Laboratory, Pune, 411008, India.

Published: March 2024

An attempt to explore the reactivity of the nitro group in the presence of gold catalysis in comparison to the azide group yielded intriguing results. Surprisingly, only the nitro group exhibited reactivity, ultimately giving rise to the formation of the title isatogen, CHNO. In the crystal structure, weak C-H⋯O hydrogen bonds and π-π stacking inter-actions link the mol-ecules. The structure exhibits disorder of the mol-ecule.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10915669PMC
http://dx.doi.org/10.1107/S2056989024001440DOI Listing

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