For continuous-time Markov chains we prove that, depending on the notion of effective affinity , the probability of an edge current to ever become negative is either 1 if else . The result generalizes a "noria" formula to multicyclic networks. We give operational insights on the effective affinity and compare several estimators, arguing that stopping problems may be more accurate in assessing the nonequilibrium nature of a system according to a local observer. Finally we elaborate on the similarity with the Boltzmann formula. The results are based on a constructive first-transition approach.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10914643 | PMC |
| http://dx.doi.org/10.1007/s10955-024-03236-5 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
A 25-Year Retrospective of Health IT Infrastructure Building: The Example of the Catalonia Region.
J Med Internet Res
November 2024
Catalan Health Service, Barcelona, Spain.
Over the past decades, health care systems have significantly evolved due to aging populations, chronic diseases, and higher-quality care expectations. Concurrently with the added health care needs, information and communications technology advancements have transformed health care delivery. Technologies such as telemedicine, electronic health records, and mobile health apps promise enhanced accessibility, efficiency, and patient outcomes, leading to more personalized, data-driven care.
View Article and Find Full Text PDFCombination of Ambient and High-Temperature Beryllium Nitride Motifs in WBeN and WBeN.
Angew Chem Int Ed Engl
November 2024
Department of Chemistry, University of Munich (LMU), Butenandtstraße 5-13, 81377, Munich, Germany.
Compounds of transition metals and beryllium have a wide range of applications, from everyday tools to high tech applications. Remarkably, no single ternary beryllium nitride with a transition metal is known. Here, we report on the synthesis and properties of the first transition metal nitridoberyllates, namely WBeN and WBeN.
View Article and Find Full Text PDFThe structural, electronic, optical, thermoelectric, and magnetic properties of the Perovskite PrFeO: DFT and Monte Carlo simulations.
J Mol Model
September 2024
Laboratory of Condensed Matter and Interdisciplinary Sciences (LaMCScI), Faculty of Sciences, Mohammed V University, Av. Ibn Batouta, B. P. 1014, Rabat, Morocco.
Context: Nowadays, Perovskite materials with diverse compositions and structures have garnered significant attention for their potential applications across various industrial and technological fields. Here, we investigated the structural, electronic, optical, thermodynamic, thermoelectric, and magnetic properties of perovskite PrFeO using density functional theory and Monte Carlo simulations. The optimization results demonstrate that the ferromagnetic phase is more stable than the antiferromagnetic phase.
View Article and Find Full Text PDFImproving healthcare transition for young people with cancer: factors fundamental to the quality improvement journey.
Br J Nurs
July 2024
Research Fellow in Transition, University of Surrey, Guildford; Lead Practice Educator-Health Inequalities, Great Ormond Street Hospital for Children NHS Foundation Trust, London; and University College London Great Ormond Street Institute of Child Health, London.
Background: Young people receiving cancer treatment in the South Thames Children's, Teenagers' and Young Adults' Cancer Operational Delivery Network usually receive care across two or more NHS trusts, meaning transition into adult services can be challenging.
Aim: To develop a planned, co-ordinated approach to transition across the network that meets National Institute for Health and Care Excellence guidance recommendations for transition and the cancer service specifications.
Methods: A 2-year, nurse-led quality improvement (QI) project, using the principles of experience-based co-design.
Desymmetrization of Cyclic Sulfonimidamides by Asymmetric Allylation.
Angew Chem Int Ed Engl
August 2024
Department of Chemistry, University of California, Davis, One Shields Ave., Davis California, 95616, United States.
Herein we report the first transition metal-catalyzed approach to the enantioenriched synthesis of cyclic sulfonimidamides relying on commercially available palladium catalysts and ligands. High-throughput experimentation (HTE) was employed to identify the optimal catalyst system and solvent. The method is applied to a variety of saturated and unsaturated rings and exhibits the highest selectivity for 2-substituted allyl electrophiles.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!