In this paper, an isophorone-based NIR fluorescent and colormetric probe BDDH for Al was synthesized and characterized, it showed highly selectivity and sensitivity through significant fluorescence enhancement and visible color change towards Al. The job plot confirmed that the binding ratio of BDDH with Al was 1:1. Furthermore, the limit of detection (LOD) of Al was determined to be 4.01 × 10 M. Moreover, BDDH was successfully applicated in identification of Al in the different water samples, cell imaging in alive MCF-7 cells and plant imaging in soybean roots.
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http://dx.doi.org/10.1016/j.saa.2024.124040 | DOI Listing |
J Hazard Mater
December 2024
Department of Chemistry, College of Arts and Sciences, Northeast Agricultural University, Harbin 150030, PR China; Key Laboratory of Agricultural Functional Molecule Design and Utilization of Heilongjiang Province, Northeast Agricultural University, Harbin 150030, China. Electronic address:
Heavy metal contamination and pesticide residues pose significant threats to human health and ecosystems. Despite its broad applications, fluorescence imaging technology often struggles in complex ecological and biological environments due to disadvantages of background autofluorescence and low quantum yield. This study introduced a near-infrared (NIR) multifunctional "off-on-off" isophorone-based fluorescent bio-probe, DHB, characterized by a high fluorescence quantum yield (10.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
May 2024
Department of Applied Chemistry, College of Science, Northeast Agricultural University, Harbin 150030, PR China. Electronic address:
In this paper, an isophorone-based NIR fluorescent and colormetric probe BDDH for Al was synthesized and characterized, it showed highly selectivity and sensitivity through significant fluorescence enhancement and visible color change towards Al. The job plot confirmed that the binding ratio of BDDH with Al was 1:1. Furthermore, the limit of detection (LOD) of Al was determined to be 4.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
March 2019
College of Chemistry and Chemical Engineering, Southeast University, Nanjing, Jiangsu 211189, China; Jiangsu Province Hi-Tech Key Laboratory for Biomedical Research, School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China. Electronic address:
Fast, highly selective and sensitive thiophenol probes are highly desirable in the field of bioimaging and environmental monitoring. For that, based on the mechanism that thiophenol can effectively cleave the sulfonamide bond selectively, we herein report a dicyanoisophorone-based Red-emitting/NIR probe for thiophenol detection. This probe had some desirable properties such as rapid response, high selectivity and sensitivity, remarkable large Stokes shift (181 nm), Red-emitting/NIR fluorescence region and low LOD value (80 nM, according to 3σ/s).
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