Chiral plasmonic nanostructures can produce strong chiral optical responses and have potential applications in photonics. Experimentally, metallic nanoparticle helices have been synthesized to achieve strong chiral responses. Strong coupling effects between the quantum emitters and the plasmon have attracted significant attention in the past decade and have been recently extended to the chiral plasmon of nanostructures. However, the strong coupling between molecules and metallic nanosphere helices has not been reported yet. In this article we study theoretically such an effect and examine the modulation of chiral and coupling effects by illumination light and molecular layer thickness. Our study may guide further experimental studies.
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http://dx.doi.org/10.1021/acs.jpclett.4c00019 | DOI Listing |
Nat Struct Mol Biol
January 2025
Key Laboratory of RNA Innovation, Science, and Engineering; Center for Excellence in Molecular Cell Science, Shanghai Institute of Biochemistry and Cell Biology, Chinese Academy of Sciences, Shanghai, China.
Lysosomal membrane protein LYCHOS (lysosomal cholesterol signaling) translates cholesterol abundance to mammalian target of rapamycin activation. Here we report the 2.11-Å structure of human LYCHOS, revealing a unique fusion architecture comprising a G-protein-coupled receptor (GPCR)-like domain and a transporter domain that mediates homodimer assembly.
View Article and Find Full Text PDFNat Commun
January 2025
School of Material Science and Engineering, Nanjing University of Science and Technology, Nanjing, 210094, People's Republic of China.
Interlayer coupling in 2D heterostructures can result in a reduction of the rotation symmetry and the generation of quantum phenomena. Although these effects have been demonstrated in transition metal dichalcogenides (TMDs) with mismatched interfaces, the role of band hybridization remains unclear. In addition, the creation of flat bands at the valence band maximum (VBM) of TMDs is still an open challenge.
View Article and Find Full Text PDFAnal Chem
January 2025
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China.
Tumor-derived extracellular vesicles (T-EVs) PD-L1 are an important biomarker for predicting immunotherapy response and can help us understand the mechanism of resistance to immunotherapy. However, this is due to the interference from a large proportion of nontumor-derived EVs. It is still challenging to accurately analyze T-EVs PD-L1 in complex human fluids.
View Article and Find Full Text PDFSci Total Environ
January 2025
Programa de Pós-Graduação em Clima e Ambiente, Instituto Nacional de Pesquisas da Amazônia, Universidade do Estado do Amazonas, Av. André Araújo, 2936, Bairro Aleixo, 69060-001 Manaus, AM, Brazil.
The teleconnections between El Niño-Southern Oscillation (ENSO), the Indian Ocean Dipole (IOD), and Tropical North Atlantic warming (+TNA) play a critical role in characterizing extreme drought events in the Amazon Basin (AB). This study examines the seven most recent drought extreme events up to 2023, using seasonal composites of the sea surface temperature and atmospheric variables over a five-quarter period starting at the austral spring(-1) of the year preceding that when the lowest water level at Manaus port was recorded. Two distinct patterns emerge, driven by consecutive ENSO events with opposite phases, referred to as cyclic La Niña-El Niño and cyclic El Niño-La Niña drought events.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, Hunan, China. Electronic address:
Heterointerface engineering is an effective strategy to design and construct high-performance photocatalysts. Herein, polyaniline (PANI) nanoparticles and ZnTi layered double hydroxide (ZnTi-LDH) nanosheets were integrated to form organic-inorganic heterostructure (PANI/LDH) via d-π electronic coupling using in-situ polymerization for photocatalytic oxidation/reduction towards tetracycline (TC) and Cr(VI). The photocatalytic activity was closely related to feed amount of aniline (Ani) in the polymerization process, which the abundant PANI nanoparticles were evenly distributed on the surface of ZnTi-LDH nanosheets at the proper Ani feed amount, and thus reinforced d-π electronic coupling at the organic-inorganic interfaces more efficiently.
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