Photocatalysis involving energy transfer (EnT) has become a valuable technique for building intricate organic frameworks mostly through [2+2]-cycloaddition reactions. Herein, we report a synthetic method leading to functionalized cyclohepta[]indoles, an important structural motif in natural products and pharmaceuticals, using gold-mediated energy transfer photocatalysis. The scope of this operationally simple and atom-economical strategy is presented. Density functional theory studies were employed in order to gain insights into the mechanism of formation of the cyclohepta[]indole core.
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