Enhancement of biohydrogen production by photo-fermentation of corn stover via visible light catalyzed titanium dioxide/activated carbon fiber.

In this study, titanium dioxide/activated carbon fiber (TiO/ACF) was synthesized by liquid-phase deposition method and the effect of TiO/ACF on the performance of photo-fermentation biohydrogen production (PFHP) from corn stover under visible light catalysis was discussed. Results show the maximum cumulative hydrogen yield (CHY) obtained under the optimal conditions was 74.0 ± 1.3 mL/g TS with TiO/ACF addition of 100 mg/L, which was twice that without TiO/ACF addition (36.9 ± 1.0 mL/g TS). Initial pH value had the most significant effect on CHY. The addition of TiO/ACF promoted the metabolic pathway of nitrogenase to reduce H produced by consuming acetic acid and butyric acid to hydrogen, and also shortened the photo-fermentation period. By scanning electron microscopy and X-ray diffraction analysis, the morphology and phase structure of TiO/ACF after PFHP did not change significantly. This study laid the foundation for the reuse of TiO and its practical application in PFHP.