Meta-atoms are the building blocks of metamaterials, which are employed to control both generation and propagation of light as well as provide novel functionalities of localization and directivity of electromagnetic radiation. In many cases, simple dielectric or metallic resonators are employed as meta-atoms to create different types of electromagnetic metamaterials. Here, we fabricate and study composed of coupled perovskite quantum dots. We reveal that these multiscale structures exhibit specific emission properties, such as spectrum splitting and polaritonic effects. We believe that such multiscale supercrystal meta-atoms will provide novel functionalities in the design of many novel types of active metamaterials and metasurfaces.
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http://dx.doi.org/10.1021/acs.nanolett.3c04580 | DOI Listing |
Adv Mater
August 2024
Department of Materials Science and Engineering, Cornell University, Ithaca, NY, 14853, USA.
Mott metal-insulator transitions possess electronic, magnetic, and structural degrees of freedom promising next-generation energy-efficient electronics. A previously unknown, hierarchically ordered, and anisotropic supercrystal state is reported and its intrinsic formation characterized in-situ during a Mott transition in a CaRuO thin film. Machine learning-assisted X-ray nanodiffraction together with cryogenic electron microscopy reveal multi-scale periodic domain formation at and below the film transition temperature (T ≈ 200-250 K) and a separate anisotropic spatial structure at and above T.
View Article and Find Full Text PDFACS Nano
April 2024
Université Paris-Saclay, CNRS, Laboratoire de Physique des Solides, 91405 Orsay, France.
Nano Lett
March 2024
Qingdao Innovation and Development Center, Harbin Engineering University, Qingdao 266000, Shandong, China.
Meta-atoms are the building blocks of metamaterials, which are employed to control both generation and propagation of light as well as provide novel functionalities of localization and directivity of electromagnetic radiation. In many cases, simple dielectric or metallic resonators are employed as meta-atoms to create different types of electromagnetic metamaterials. Here, we fabricate and study composed of coupled perovskite quantum dots.
View Article and Find Full Text PDFNanoscale Adv
October 2022
Department of Physics and Astronomy, The University of Texas at San Antonio, One UTSA Circle San Antonio Texas 78249 USA
Computational modeling of plasmonic periodic structures are challenging due to their multiscale nature. On one hand, nanoscale building blocks require very fine spatial discretization of the computation domain to describe the near-field nature of the localized surface plasmons. On the other hand, the microscale supercrystals require large simulation domains.
View Article and Find Full Text PDFSci Rep
March 2019
Institute of Advanced Ceramics, Hamburg University of Technology, 21073, Hamburg, Germany.
Biomaterials often display outstanding combinations of mechanical properties thanks to their hierarchical structuring, which occurs through a dynamically and biologically controlled growth and self-assembly of their main constituents, typically mineral and protein. However, it is still challenging to obtain this ordered multiscale structural organization in synthetic 3D-nanocomposite materials. Herein, we report a new bottom-up approach for the synthesis of macroscale hierarchical nanocomposite materials in a single step.
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