Fiber reinforced concrete (FRC) is attracting many researchers' attention due to its excellent mechanical and fracture properties. However, its widespread implementation is hampered by the issues related to the dispersion and orientation of its fibers. According to the fracture mechanics, the reinforcement would provide maximum bridging when placed perpendicular to the crack propagation. This study is focused on the magnetic-based orientation of synthetic fibers which are mostly used in strain hardening FRC also termed as Engineered Cementitious Composites (ECC). Initially, the PVA fibers were coated with waste iron particles using a hydrothermal synthesis procedure. This was done to make synthetic fibers magnetically responsive by the formation of a physical bond between iron and PVA fibers. A solenoid was used to provide a high-intensity magnetic flux to orient these fibers in the direction of magnetic lines. Three different ECC mixes were prepared and cast in wooden molds. The molds were then placed one by one into the magnetic field for the orientation of the fibers. The fibers were successfully aligned perpendicular to the flexure cracks in only flexure dominant regions with the aid of a magnetic field. The orientation of fibers was verified with the help of microscopic images of the tortured surfaces. As a result of well aligned fibers dispersed in the ECC mix, the flexural strength was increased by 21%.
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http://dx.doi.org/10.1016/j.heliyon.2024.e26056 | DOI Listing |
Sci Rep
January 2025
Department of Pharmacology, Faculty of Science, Mahidol University, Bangkok, 10400, Thailand.
Sutures from natural and synthetic materials are utilized to close wounds, stop bleeding, reduce pain and infection, repair cutaneous wounds, minimize scarring, and promote optimal wound healing. We used mechanical and chemical methods to extract cellulose fibers from cylindrical snake grass (Dracaena angolensis) (Welw. ex Carrière) Byng & Christenh.
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January 2025
Biosciences Division, Oak Ridge National Laboratory, Oak Ridge, TN, USA.
For decades, Agrobacterium tumefaciens-mediated plant transformation has played an integral role in advancing fundamental and applied plant biology. The recent omnipresent emergence of synthetic biology, which relies on plant transformation to manipulate plant DNA and gene expression for novel product biosynthesis, has further propelled basic as well as applied interests in plant transformation technologies. The strong demand for a faster design-build-test-learn cycle, the essence of synthetic biology, is, however, still ill-matched with the long-standing issues of high tissue culture recalcitrance and low transformation efficiency of a wide range of plant species especially food, fiber and energy crops.
View Article and Find Full Text PDFTalanta
January 2025
Ministry of Education (MOE) Key Laboratory of Bioinorganic and Synthetic Chemistry, Ministry of Education, School of Chemistry, Sun Yat-sen University, Guangzhou, 510006, PR China; School of Chemical Engineering and Technology, Sun Yat-sen University, and Southern Marine Science and Engineering Guangdong Laboratory (Zhuhai), 519082, Zhuhai, PR China; Guangdong Provincial Key Laboratory of Emergency Test for Dangerous Chemicals, Guangdong Provincial Engineering Research Center for Ambient Mass Spectrometry, Institute of Analysis, Guangdong Academy of Sciences (China National Analytical Center Guangzhou), 100 Xianlie Middle Road, Guangzhou, 510070, PR China; Chemistry College, Center of Advanced Analysis and Gene Sequencing, Zhengzhou University, Kexue Avenue 100, Zhengzhou, 450001, PR China.
Macrocyclic polymer materials exhibit excellent selectivity and adsorption performance in pollutant adsorption due to unique host-guest recognition. Herein, three kinds of calixarene polymers (C4P, C6P and C8P) were synthesized through Sonogashira reaction, and were characterized through H NMR, FT-IR, SEM, and TEM. The water contact angle experiments revealed that three kinds of calixarene polymers were highly hydrophobic, and they all exhibited high enrichment efficiency for weak polar chloro-substituted benzene compounds (chlorobenzene, o-chlorotoluene, p-dichlorobenzene and o-dichlorobenzene) and BTEX (benzene, toluene, ethylbenzene and xylenes).
View Article and Find Full Text PDFNanomicro Lett
January 2025
Department of Chemical Engineering, The Pennsylvania State University, University Park, PA, 16802, USA.
Plant cell wall (CW)-like soft materials, referred to as artificial CWs, are composites of assembled polymers containing micro-/nanoparticles or fibers/fibrils that are designed to mimic the composition, structure, and mechanics of plant CWs. CW-like materials have recently emerged to test hypotheses pertaining to the intricate structure-property relationships of native plant CWs or to fabricate functional materials. Here, research on plant CWs and CW-like materials is reviewed by distilling key studies on biomimetic composites primarily composed of plant polysaccharides, including cellulose, pectin, and hemicellulose, as well as organic polymers like lignin.
View Article and Find Full Text PDFACS Nano
January 2025
iLoF-Intelligent Lab on Fiber, Rua de Godim 389, 4300 Porto, Portugal.
Nanocarriers (NCs) have emerged as a revolutionary approach in targeted drug delivery, promising to enhance drug efficacy and reduce toxicity through precise targeting and controlled release mechanisms. Despite their potential, the clinical adoption of NCs is hindered by challenges in their physicochemical characterization, essential for ensuring drug safety, efficacy, and quality control. Traditional characterization methods, such as dynamic light scattering and nanoparticle tracking analysis, offer limited insights, primarily focusing on particle size and concentration, while techniques like high-performance liquid chromatography and mass spectrometry are hampered by extensive sample preparation, high costs, and potential sample degradation.
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