Synthesis of Network Biobased Aliphatic Polyesters Exhibiting Better Tensile Properties than the Linear Polymers by ADMET Polymerization in the Presence of Glycerol Tris(undec-10-enoate).

Development of biobased aliphatic polyesters with better mechanical (tensile) properties in film has attracted considerable attention. This report presents the synthesis of soluble network biobased aliphatic polyesters by acyclic diene metathesis (ADMET) polymerization of bis(undec-10-enyl)isosorbide diester [, dianhydro--glucityl bis(undec-10-enoate)] in the presence of a tri-arm crosslinker [, glycerol tris(undec-10-enoate)] using a ruthenium-carbene catalyst, and subsequent olefin hydrogenation using RhCl(PPh). The resultant polymers, after hydrogenation (expressed as ) and prepared in the presence of 1.0 mol% , showed better tensile properties than the linear polymer () with similar molecular weight [tensile strength (elongation at break): 20.8 MPa (282%) in vs. 35.4 MPa (572%) in ]. It turned out that the polymer films prepared by the addition of during the polymerization (expressed as a 2-step approach) showed better tensile properties. The resultant polymer film also shows better tensile properties than the conventional polyolefins such as linear high density polyethylene, polypropylene, and low density polyethylene.