Reaction of [CuH(PPh)] with 1 equiv. of Tl(OTf) results in formation of [CuTlH(PPh)][OTf] ([1]OTf]), which can be isolated in good yields. Variable-temperature H NMR spectroscopy, in combination with density functional theory (DFT) calculations, confirms the presence of a rare Tl-H orbital interaction. According to DFT, the H chemical shift of the Tl-adjacent hydride ligands of [1] includes 7.7 ppm of deshielding due to spin-orbit effects from the heavy Tl atom. This study provides valuable new insights into a rare class of metal hydrides, given that [1][OTf] is only the third isolable species reported to contain a Tl-H interaction.
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