-Oligosaccharides are metabolically stable surrogates of native glycans containing //-glycosidic linkages and thus have therapeutic potential. Here we report a straightforward approach to the synthesis of vinyl -linked oligosaccharides via the Ni-catalyzed reductive hydroglycosylation of alkynyl glycosides with glycosyl bromides.
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| http://dx.doi.org/10.1021/acs.orglett.4c00289 | DOI Listing |
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