Unsupervised domain adaptation (UDA) aims to alleviate the domain shift by transferring knowledge learned from a labeled source dataset to an unlabeled target domain. Although UDA has seen promising progress recently, it requires access to data from both domains, making it problematic in source data-absent scenarios. In this article, we investigate a practical task source-free domain adaptation (SFDA) that alleviates the limitations of the widely studied UDA in simultaneously acquiring source and target data. In addition, we further study the imbalanced SFDA (ISFDA) problem, which addresses the intra-domain class imbalance and inter-domain label shift in SFDA. We observe two key issues in SFDA that: 1) target data form clusters in the representation space regardless of whether the target data points are aligned with the source classifier and 2) target samples with higher classification confidence are more reliable and have less variation in their classification confidence during adaptation. Motivated by these observations, we propose a unified method, named intrinsic consistency preservation with adaptively reliable samples (ICPR), to jointly cope with SFDA and ISFDA. Specifically, ICPR first encourages the intrinsic consistency in the predictions of neighbors for unlabeled samples with weak augmentation (standard flip-and-shift), regardless of their reliability. ICPR then generates strongly augmented views specifically for adaptively selected reliable samples and is trained to fix the intrinsic consistency between weakly and strongly augmented views of the same image concerning predictions of neighbors and their own. Additionally, we propose to use a prototype-like classifier to avoid the classification confusion caused by severe intra-domain class imbalance and inter-domain label shift. We demonstrate the effectiveness and general applicability of ICPR on six benchmarks of both SFDA and ISFDA tasks. The reproducible code of our proposed ICPR method is available at https://github.com/CFM-MSG/Code_ICPR.
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http://dx.doi.org/10.1109/TNNLS.2024.3362948 | DOI Listing |
J Mol Model
January 2025
Department of Theoretical Chemistry, Faculty of Chemistry, Jagiellonian University, Gronostajowa 2, 30-387, Krakow, Poland.
Context: The analysis of the changes in the electronic structure along intrinsic reaction coordinate (IRC) paths for model reactions: (i) ethylene + butadiene cycloaddition, (ii) prototype SN2 reaction Cl + CH3Cl, (iii) HCN/CNH isomerization assisted by water, (iv) CO + HF → C(O)HF was performed, in terms of changes in the deformation density (Δr) and the deformation of MEP (ΔMEP). The main goal was to further examine the utility of the ΔMEP as a descriptor of chemical bonding, and to compare the pictures resulting from Δr and ΔMEP. Both approaches clearly show that the main changes in the electronic structure occur in the TS region.
View Article and Find Full Text PDFBackground: Passively-obtained smartphone digital phenotypes may yield objective estimates of everyday cognition in older adults compared to traditional cognitive/self-report measures typically confounded by sociodemographics. However, it is currently unknown what covariates are relevant when interpreting smartphone sensor data. We aimed to clarify which intrinsic and extrinsic factors are associated with digital phenotyping versus traditional cognitive measures in a cohort of older adults.
View Article and Find Full Text PDFPhys Chem Chem Phys
January 2025
Center for Nanoscience and Sustainable Technologies (CNATS), Universidad Pablo de Olavide, 41013 Seville, Spain.
The proton bond is a pivotal chemical motif in many areas of science and technology. Its quantum chemical description is remarkably challenged by nuclear and charge delocalization effects and the fluxional perturbation that it induces on molecular substrates. This work seeks insights into proton bonding at sub-kelvin temperatures.
View Article and Find Full Text PDFAdv Mater
January 2025
Institute of Functional Nano & Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, 199 Ren'ai Road, Suzhou, Jiangsu, 215123, China.
The electrochemical two-electron oxygen reduction reaction (2e ORR) offers a sustainable pathway for the production of HO; however, the development of electrocatalysts with exceptional activity, selectivity, and long-term stability remains a challenging task. Herein, a novel approach is presented to addressing this challenge by synthesizing hierarchical hollow SmPO nanospheres with open channels via a two-step hydrothermal treatment. The produced compound demonstrates remarkable 2e selectivity, exceeding 93% across a wide potential range of 0.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Physics and Astronomy, and Institute of Applied Physics, Seoul National University, Seoul, Korea.
Addressing and mitigating decoherence sources plays an essential role in the development of a scalable quantum computing system, which requires low gate errors to be consistently maintained throughout the circuit execution. While nuclear spin-free materials, such as isotopically purified silicon, exhibit intrinsically promising coherence properties for electron spin qubits, the omnipresent charge noise, when converted to magnetic noise under a strong magnetic field gradient, often hinders stable qubit operation within a time frame comparable to the data acquisition time. Here, we demonstrate both open- and closed-loop suppression techniques for the transduced noise in silicon spin qubits, resulting in a more than two-fold (ten-fold) improvement of the inhomogeneous coherence time (Rabi oscillation quality) that leads to a single-qubit gate fidelity of over 99.
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