Ring-opening isomerization polymerization was developed using a combination of a ring-opening reaction of epoxides and subsequent Brook rearrangement. An epoxy monomer with a benzyltrimethylsilyl group was designed for the polymerization. Characterization of the obtained polymer by NMR and MALDI-TOF-MS indicated that polymerization proceeded exclusively a ring-opening-isomerization anionic polymerization mechanism.
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Ring-opening-isomerization anionic polymerization Brook rearrangement.
Chem Commun (Camb)
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Faculty of Molecular Chemistry and Engineering, Kyoto Institute of Technology, Matsugasaki, Sakyo-ku, Kyoto 606-8585, Japan.
Ring-opening isomerization polymerization was developed using a combination of a ring-opening reaction of epoxides and subsequent Brook rearrangement. An epoxy monomer with a benzyltrimethylsilyl group was designed for the polymerization. Characterization of the obtained polymer by NMR and MALDI-TOF-MS indicated that polymerization proceeded exclusively a ring-opening-isomerization anionic polymerization mechanism.
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