This work reports a strategy by enhancing conjugation effect and synthesizes a symmetrical and planar compound, 1,2-bis (4,5-di(1-tetrazol-5-yl)-2-1,2,3-triazol-2-yl)diazene (). The incorporation of azo and 1,2,3-triazole moieties manifests a synergistic effect, amplifying the conjugation effect of the azo bridge and thereby elevating the stability of (: 263 °C, IS: 7 J). Notably, , possessing a structural configuration comprising four tetrazoles harboring a total of 24 nitrogen atoms, exhibits excellent detonation performances (Δ: 6.06 kJ g, : 9002 m s). This strategy achieves the balance of energy and stability of polycyclic tetrazoles and provides a direction for high-performance energetic materials.
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