Forward scattering is an essential tool for investigating the colloidal suspension of polystyrene microspheres (PSMs). Evanescent wave coupled cavity ringdown spectroscopy (EW-CRDS) shows the anomalous extinction behavior in the limit of PSM particles that is much larger than the wavelength. EW-CRDS is a highly sensitive technique that improves weak absorption signals by enhancing the absorption path length, allowing for probing a range of processes at the solid/liquid interface by assessing the extinction properties. Additionally, it possesses the ability to sense a minimum absorbance of 1.2 × 10. EW-CRDS provides sufficient accuracy to detect correlation effects for PSMs in water at the interfacial region and their influence on forward scattering or extinction. In this work, we discuss the impact of volume fraction on the extinction of scatterers composed of microparticles in aqueous media. The findings of this study will contribute to a deeper understanding of the scattering dynamics in colloidal suspensions, with potential applications in various fields, including biology and metrology.
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http://dx.doi.org/10.1039/d3an02225k | DOI Listing |
Biosens Bioelectron
January 2025
Innovation Center of Functional Genomics and Molecular Diagnostics Technology of Gansu Province, Lanzhou, China.
Improving the sensitivity of biosensor has always the major challenge to measure lower detection concentration of biological samples. In this paper, a novel optical fiber surface plasmon resonance (SPR) biosensor based on TiC MXene/GNRs synergistically highly enhanced sensitivity was proposed. The TiC MXene and GNRs were coated on the optical fiber sensing probe by the electrostatic layer-by-layer (ELBL) assembly method.
View Article and Find Full Text PDFNat Commun
January 2025
Chimie du Solide et de l'Énergie, UMR 8260, Collège de France, Paris, France.
As batteries drive the transition to electrified transportation and energy systems, ensuring their quality, reliability, lifetime, and safety is crucial. While the solid electrolyte interphase (SEI) is known to govern these performance characteristics, its dynamic nature makes understanding its nucleation, growth, and composition an ambitious, yet elusive aspiration. This work employs chalcogenide fibres embedded in negative electrode materials for operando Infra-red Fibre-optic Evanescent Wave Spectroscopy (IR-FEWS), combined with Multivariate Curve Resolution by Alternating Least Squares (MCR-ALS) algorithms for spectra analysis.
View Article and Find Full Text PDFBiosens Bioelectron
January 2025
Institute of Physics, College of Natural Sciences, University of Rzeszow, Rzeszow, Poland.
Fabry disease (FD) is a rare disorder resulting from a genetic mutation characterized by the accumulation of sphingolipids in various cells throughout the human body, leading to progressive and irreversible organ damage, particularly in males. Genetically-determined deficiency or reduced activity of the enzyme (alpha - Galactosidase; α-Gal) leads to the accumulation of sphingolipids in the lysosomes of various cell types, including the heart, kidneys, skin, eyes, central nervous system, and digestive system, triggering damage, leading to the failure of vital organs, and resulting in progressive disability and premature death. FD diagnostics currently depend on costly and time-intensive genetic tests and enzymatic analysis, often leading to delayed or inaccurate diagnoses, which contribute to rapid disease progression.
View Article and Find Full Text PDFWe demonstrate the heterogeneous integration of GaInAsSb-GaSb photodiodes on 220 nm SOI photonic integrated circuits (PICs) using the micro-transfer-printing (μTP) technology, for operation in the short-wave infrared (SWIR) wavelength region. Utilizing an evanescent coupling scheme between a silicon waveguide and a III-V structure, the device exhibits a room temperature responsivity of 1.23 and 1.
View Article and Find Full Text PDFThe intermediate phase produced by the complexation of metal ions and solvent molecules usually occurs in the crystallization process of perovskite single crystal or film. Effective monitoring of intermediate-phase evolution is beneficial to the control of crystal quality. However, it is difficult to realize.
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