Considering the instability and toxicity of 3D Pb-based perovskite nanocrystals, lead-free low-dimensional organic-inorganic hybrid metal halides have attracted widespread attention as potential substitutes. Herein, two new tin-based 0D halides [HBAPP]SnBr·Br and [HBAPP]SnCl·Cl·HO (BAPP = 1,4-bis(3-aminopropyl)piperazine) were synthesized successfully based on [SnX] as an emission center. Typically, [HBAPP]SnBr·Br and [HBAPP]SnCl·Cl·HO display broadband yellow and yellow-green light emissions originating from the radiative recombination of self-trapped excitons (STEs). The photoluminescence quantum yields (PLQYs) of the two compounds were calculated to be 19.27% and 2.36%, respectively. Furthermore, the excellent chemical and thermal stability and broadband light emissions reveal their potential application in solid-state white lighting diodes.
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