Preparation of nanostructured photocatalyst ZnSnO@S-doped g-CN and its use in DB1 dye degradation through photocatalytic ozonation process.

This study aimed to investigate the potential of the photocatalytic ozonation process (PCO) for decolorizing DB1(direct blue) dye, a commonly used dye in the textile industry known for its resistance to removal from wastewater. To address this challenge, a ZnSnO@S-doped g-CN nano photocatalyst was synthesized using a simple hydrothermal method. In a novel approach, a light/O/ZnSnO@S-doped g-CN system was employed for the first time to degrade the DB1 dye. BET analysis indicated that the synthesized catalyst exhibited the fifth type of isotherm, typically associated with materials containing mesopores. Under optimized conditions, the PCO process achieved complete decolorization of 70 ppm DB1 dye within just 15 min at a temperature of 25 °C, a gas flow rate of 2.83 ml/s, and a catalyst dosage of 0.003 g, encompassing both removal and photocatalytic contributions. Importantly, the catalyst demonstrated excellent stability and could be reused up to five times. These findings highlight the promising potential of the light/O/ZnSnO@S-doped g-CN system in effectively decolorizing DB1 dye, overcoming its resistance, and addressing an important challenge faced by the textile industry in wastewater treatment. The formative nature of this study provides valuable insights into the development of advanced oxidation processes for efficient dye removal.