Soft wetting: Substrate softness- and time-dependent droplet/bubble adhesion.

Hypothesis: The droplet/bubble adhesion characteristics depend on the length of the droplet/bubble three-phase contact line. Since the deformation caused by the liquid-gas interfacial tension on the soft substrate, referred as to the wetting ridge, retards contact line spreading and retraction, we conjecture that the droplet/bubble adhesion characteristics depend also on the substrate softness.

Experiments: Soft substrates with various shear moduli are prepared and characterized by the spreading and receding dynamics of water droplets and underwater bubbles. Snap-in and normal adhesion forces of droplets/bubbles on such soft substrates are directly measured along with the visualized droplet/bubble shape profiles.

Findings: The droplet/bubble snap-in force, which corresponds to the short-time spreading dynamics, decreases with a decrease in the substrate shear modulus because of the retarded contact line spreading. The droplet maximal adhesion force on a soft substrate can be counterintuitively either smaller or larger than its counterpart on the rigid substrate depending on different dwelling times, i.e., the droplet/bubble-substrate contact time before droplet/bubble-substrate separation. The former is attributed to the retarded contact line spreading, whereas the latter is attributed to the retarded contact line retraction. The substrate softness- and dwelling time-dependent droplet/bubble adhesion reported in this study will benefit various applications related to soft substrates.