The properties of nanostructured networks of conductive materials have been extensively studied under the lens of percolation theory. In this work, we introduce a novel type of local percolation phenomenon used to investigate the conduction properties of a new hybrid material that combines sparse metallic nanowire networks and fractured conducting thin films on flexible substrates. This original concept could potentially lead to the design of a novel composite transparent conducting material. Using a complementary approach including formal analytical derivations, Monte Carlo simulations and electrical circuit representation for the modelling of bridged-percolating nanowire networks, we unveil the key relations between linear crack density, nanowire length and network areal mass density that ensure electrical percolation through the hybrid. The proposed theoretical model provides key insights into the conduction mechanism associated with the original concept of bridge percolation in random nanowire networks.
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http://dx.doi.org/10.1039/d3nr05850f | DOI Listing |
ACS Appl Mater Interfaces
January 2025
School of Medicine, Huanghe Science and Technology University, Zhengzhou 450061, P. R. China.
Silver nanowire (Ag NW)-based elastic conductors have been considered a promising candidate for key stretchable electrodes in wearable devices. However, the weak interface interaction of Ag NWs and elastic substrates leads to poor durability of electronic devices. For everyday usage, an additional self-healing ability is required to resist scratching and damage.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
January 2025
Beihang University, School of Chemistry, chemsitry, No 37 Xueyuan Rd, 100191, Beijing, CHINA.
Achieving multi-spectrum compatible stealth in radar-terahertz-infrared bands with robust performance has great prospects for both military and civilian applications. However, the progress of materials encounters substantial challenges due to the significant variability in frequency coupling properties across different electromagnetic wave bands. Here, this work presents the design of a multi-scale structure and fabricates a lightweight aerogel (silver nanowire@carbon, AgNW@C) consisting of a regular coaxial nano-cable, with silver nanowire as the core and amorphous-graphitized hybrid carbon as the outer-layer.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
ARC Centre of Excellence in Exciton Science, School of Chemistry, University of Melbourne, Parkville, VIC 3010, Australia.
Effective heat management is critical for improving energy efficiency and minimizing environmental impact. Passive radiative heat management systems rely on specific materials and design configurations to naturally modulate temperature, enhance system reliability, and decrease operational costs by modulating infrared light. However, their static nature proves insufficient in dynamic settings experiencing significant temperature fluctuations.
View Article and Find Full Text PDFNanotechnology
December 2024
Taiyuan University of Technology, College of Materials Science and Engineering, Taiyuan University of Technology, Taiyuan, 030024, China, Taiyuan, Shanxi , 030024, CHINA.
The performance of sliver nanowire (AgNWs) network flexible transparent electrodes is limited by large contact resistance, making it necessary to perform nanowelding to improve conductivity of the network. However, not all nanowire junctions can be welded. Our work indicates that the welding kinetics between nanowires depend on the crossing angle, with higher surface diffusion velocity prone to welding and fracture at nanowire junctions of crossing angles close to 90 degrees.
View Article and Find Full Text PDFInt J Biol Macromol
December 2024
Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, School of Chemistry and Chemical Engineering, Guangxi University, No. 100, Daxuedong Road, Xixiangtang District, Nanning 530004, China. Electronic address:
Humidity and temperature sensors are considered as hotspots for the next generation of wearable multifunctional electronics. However, it is still a notable challenge to realize multifunctional sensors with high-performance humidity response, excellent mechanical properties, and accurate temperature monitoring capability. In this work, a hydrogen-bond cross-linked hybrid network was constructed between carboxystyrene-butadiene rubber (XSBR) and hydrophilic carboxylated cellulose nanofibers (CNF) noncovalently modified silver nanowires (AgNWs).
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