An Analysis of the Critical Region of Multiparameter Equations of State.

Int J Thermophys

Applied Chemicals and Materials Division, National Institute of Standards and Technology, 325 Broadway, Boulder, CO 80305, USA.

Published: January 2023

In this work, two classes of defects with multiparameter equations of state are investigated. In the first, it is shown that the critical point provided by equation of state developers often does not exactly meet the criticality conditions based on the first two density derivatives of the pressure being zero at the critical point. Based on the more accurate locations of the critical points given in the first part, the scaling of the densities along the binodal and spinodal in the critical region are investigated, and we find that the vast majority of equations have reasonable behavior but a few do not.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10840457PMC
http://dx.doi.org/10.1007/s10765-023-03261-8DOI Listing

Publication Analysis

Top Keywords

critical region
8
multiparameter equations
8
equations state
8
critical point
8
analysis critical
4
region multiparameter
4
state work
4
work classes
4
classes defects
4
defects multiparameter
4

Similar Publications

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!