AI Article Synopsis
- The DUT-4 metal-organic framework (MOF) undergoes a structural transformation from an ordered to a distorted phase when exposed to ambient conditions.
- Various analytical techniques, including X-ray diffraction, Raman and FTIR spectroscopy, scanning electron microscopy, and thermal analysis, were utilized to study this transformation.
- The phase transition responds reversibly to factors like exposure time and humidity, indicating potential for new MOF-based materials in optoelectronic applications.
Article Abstract
The threshold structural transformation of the DUT-4 metal-organic framework (MOF) from an ordered to distorted phase during exposure to ambient conditions has been revealed. The X-ray diffraction analysis, Raman and FTIR spectroscopy, scanning electron microscopy and synchronous thermal analysis have been used for investigation. The reversible effect of exposure time and humidity on such a phase transition has been confirmed. We also demonstrated that the observed phase transition correlated well with changes in the optical and electronic properties of DUT-4, paving the way to a new family of MOF-based phase change materials for optoelectronic applications.
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| http://dx.doi.org/10.1039/d4dt00038b | DOI Listing |
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