The reaction of cadmium bromide tetra-hydrate with 3-amino-pyrazole (3-apz) in ethano-lic solution leads to tautomerization of the ligand and the formation of crystals of the title compound, -poly[[di-bromido-cadmium(II)]-bis-(μ-3-amino-1-pyrazole)-κ : ;κ : ], [CdBr(CHN)] or [CdBr(3-apz)]. Its asymmetric unit consists of a half of a Cd cation, a bromide anion and a 3-apz mol-ecule. The Cd cations are coordinated by two bromide anions and two 3-apz ligands, generating -CdNBr octa-hedra, which are linked into chains by pairs of the bridging ligands. In the crystal, the ligand mol-ecules and bromide anions of neighboring chains are linked through inter-chain hydrogen bonds into a two-dimensional network. The inter-molecular contacts were qu-anti-fied using Hirshfeld surface analysis and two-dimensional fingerprint plots, revealing the relative qu-anti-tative contributions of the weak inter-molecular contacts.
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| http://dx.doi.org/10.1107/S2056989023009751 | DOI Listing |
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