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Excitonic Polarons and Self-Trapped Excitons from First-Principles Exciton-Phonon Couplings. | LitMetric

Excitonic Polarons and Self-Trapped Excitons from First-Principles Exciton-Phonon Couplings.

Phys Rev Lett

Oden Institute for Computational Engineering and Sciences, The University of Texas at Austin, Austin, Texas 78712, USA and Department of Physics, The University of Texas at Austin, Austin, Texas 78712, USA.

Published: January 2024

AI Article Synopsis

Article Abstract

Excitons consist of electrons and holes held together by their attractive Coulomb interaction. Although excitons are neutral excitations, spatial fluctuations in their charge density couple with the ions of the crystal lattice. This coupling can lower the exciton energy and lead to the formation of a localized excitonic polaron or even a self-trapped exciton in the presence of strong exciton-phonon interactions. Here, we develop a theoretical and computational approach to compute excitonic polarons and self-trapped excitons from first principles. Our methodology combines the many-body Bethe-Salpeter approach with density-functional perturbation theory and does not require explicit supercell calculations. As a proof of concept, we demonstrate our method for a compound of the halide perovskite family.

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http://dx.doi.org/10.1103/PhysRevLett.132.036902DOI Listing

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