Sensitive, accurate, and reliable detection of explosives has become one of the major needs for international security and environmental protection. Colloidal quantum dots, because of their unique chemical, optical, and electrical properties, as well as easy synthesis route and functionalization, have demonstrated high potential to meet the requirements for the development of suitable sensors, boosting the research in the field of explosive detection. Here, we critically review the most relevant research works, highlighting three different mechanisms for explosive detection based on colloidal quantum dots, namely photoluminescence, electrochemical, and chemoresistive sensing. We provide a comprehensive overview and an extensive discussion and comparison in terms of the most relevant sensor parameters. We highlight advantages, limitations, and challenges of quantum dot-based explosive sensors and outline future research directions for the advancement of knowledge in this surging research field.
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http://dx.doi.org/10.1021/acssensors.3c02097 | DOI Listing |
J Am Chem Soc
January 2025
McKetta Department of Chemical Engineering and Texas Material Institute, The University of Texas at Austin, Austin, Texas 78712, United States.
Germanium (Ge) colloidal quantum dots (CQDs) were synthesized by thermal decomposition of GeI using capping ligand mixtures of oleylamine (OAm), octadecene (ODE), and trioctylphosphine (TOP). Average diameters could be tuned across a wide range, from 3 to 18 nm, by adjusting reactant concentrations, heating rates, and reaction temperatures. OAm promotes decomposition of GeI to Ge and serves as a weakly bound capping ligand.
View Article and Find Full Text PDFNat Commun
January 2025
Department of Physics "A. Pontremoli", University of Milan, via Celoria 16, 20133, Milan, Italy.
Topological defects are singularities within a field that cannot be removed by continuous transformations. The definition of these irregularities requires an ordered reference configuration, calling into question whether they exist in disordered materials, such as glasses. However, recent work suggests that well-defined topological defects emerge in the dynamics of glasses, even if they are not evident in the static configuration.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
School of Chemistry, South China Normal University, Guangzhou 510006, China. Electronic address:
Transition metal oxides (TMOs), especially zinc- and iron-based materials, are known to be one of the most innovative anode materials based on their high theoretical capacity, low price and abundant natural reserves. However, the application of these materials is limited by poor electronic conductivity, slow ion mobility and large structural transformations during charging/discharging processes. To overcome these drawbacks, sacrificial template technology has been proposed as a promising strategy to optimize the electrochemical performance and structure stability of TMOs, showing its potential especially in the storage design of lithium-ion batteries (LIBs).
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
School of Life Science and Technology, Wuhan Polytechnic University, Wuhan 430023, China. Electronic address:
With the unique photo-physical properties and strong bio-compatibility. Quantum dots (QDs) have sparked interest in biomedical fields such as imaging, biosensing and therapeutics. However, the low stability and insufficient tumor specificity have largely constrained their potential biomedical applications.
View Article and Find Full Text PDFJ Colloid Interface Sci
December 2024
School of Health Sciences, Stopford Building, The University of Manchester, Oxford Road, Manchester M13 9PT, UK.
Hypothesis: Nanoscale characterisation of the self-associated species formed by amphiphilic pharmaceuticals in aqueous solution carries relevance across their entire journey from development through to manufacture - relevant, therefore, not only as regards formulation of the drug products as medicines, but also potentially relevant to their bioavailability, activity, and clinical side effects. Such knowledge and understanding, however, can only be fully secured by applying a range of experimental and theoretical methodologies.
Experiments: Herein, we apply a synergistic combination of solubility, surface tension, SANS, NMR and UV spectroscopic studies, together with MD simulation and QM calculations, to investigate the meso-structures of propranolol hydrochloride aggregates in bulk aqueous solutions, at concentrations spanning 2.
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