MoNP-doped Defective Carbon Fibers with Bark-like Nanosurface as Effective Bifunctional Electrocatalysts for Zn-air Batteries.

The flexible air electrode with high oxygen electrocatalytic performance and outstanding stability under various deformations plays a vital role in high-performance flexible Zn-air batteries (ZABs). Herein, a self-supported Mo, N, and P co-doped carbon cloth (CC) denoted as MoNP@CC with bark-like surface structure is fabricated by a facile two-step approach via a one-pot method and pyrolysis. The surface of the electrode shows a nanoscale "rift valley" and uniformly distributed active sites. Taking advantage of the nano-surface as well as transition metal and heteroatom doping, the self-supported electrocatalysis air electrode exhibits considerable oxygen evolution reaction (OER) and oxygen reduction reaction (ORR) performance in terms of low overpotential (388 mV at 10 mA cm) for OER and a much positive potential (0.74 V) at 1.0 mA cm for ORR. Furthermore, MoNP@CC is further used for the flexible ZAB to demonstrate its practical application. The MoNP@CC-based ZAB displays a good cycling performance for 2800 min and an open-circuit voltage of 1.44 V. This work provides a new approach to the construction of a high-performance, self-supported electrocatalysis electrode used for a flexible energy storage device.