The eddy covariance (EC) technique has emerged as the most widely used method for long-term continuous methane flux (FCH) observations. However, the completeness of the FCH time series is limited by instrumental failures and data quality issues, resulting in missing data gaps ranging from 20 % to 90 %. In this situation, the excellent performance of machine learning (ML) algorithms in filling missing FCH data has provided a foundation for developing regional-scale FCH models. In this study, we established estimation models for FCH utilizing random forest (RF), support vector machine (SVM), back propagation (BP) and nonlinear multiple regression (MLR) algorithms. The maximal information coefficient (MIC) technique was employed to identify and rank the environmental factors that were correlated with FCH. Our findings revealed that soil temperature (Ts), soil water content (SWC) and air temperature (Ta) were the primary environmental factors influencing FCH. Among the four algorithms, from perspectives of model accuracy and relatively small number of driving factors, the RF models exhibited the best performance, followed by BP and SVM, whereas MLR demonstrated the lowest performance. Among the 144 RF models established using nine datasets, RF model with 8 driving factors in all-year (RF) could capture seasonal variations. Ultimately, we recommend (RF as the optimal model for estimating FCH in the Dajiuhu subalpine peatland.
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http://dx.doi.org/10.1016/j.scitotenv.2024.170241 | DOI Listing |
New Phytol
January 2025
Centre of Excellence PLECO (Plants and Ecosystems), Department of Biology, University of Antwerp, Universiteitsplein 1, B-2610, Wilrijk, Belgium.
Recent studies have shown that stem fluxes, although highly variable among trees, can alter the strength of the methane (CH) sink or nitrous oxide (NO) source in some forests, but the patterns and magnitudes of these fluxes remain unclear. This study investigated the drivers of subdaily and seasonal variations in stem and soil CH, NO and carbon dioxide (CO) fluxes. CH, NO and CO fluxes were measured continuously for 19 months in individual stems of two tree species, Eperua falcata (Aubl.
View Article and Find Full Text PDFNat Commun
January 2025
Research Center for Solar Driven Carbon Neutrality, School of Physics Science and Technology, In-stitute of Life Science and Green Development, Hebei University, Baoding, 071002, PR China.
Photo-oxidation of methane (CH) using hydrogen peroxide (HO) synthesized in situ from air and water under sunlight offers an attractive route for producing green methanol while storing intermittent solar energy. However, in commonly used aqueous-phase systems, photocatalysis efficiency is severely limited due to the ultralow availability of CH gas and HO intermediate at the flooded interface. Here, we report an atomically modified metal-organic framework (MOF) membrane nanoreactor that promotes direct CH photo-oxidation to methanol at the gas-solid interface in a reticular open framework.
View Article and Find Full Text PDFSci Total Environ
January 2025
Sarawak Tropical Peat Research Institute, Kota Samarahan, Malaysia.
Tropical peatlands are significant sources of methane (CH₄), but their contribution to the global CH₄ budget remains poorly quantified due to the lack of long-term, continuous and high-frequency flux measurements. To address this gap, we measured net ecosystem CH exchange (NEE-CH) using eddy covariance technique throughout the conversion of a tropical peat swamp forest to an oil palm plantation. This encompassed the periods before, during and after conversion periods from 2014 to 2020, during which substantial environmental shifts were observed.
View Article and Find Full Text PDFEnviron Res
January 2025
Key Laboratory of Ecosystem Network Observation and Modeling, Institute of Geographic Sciences and Natural Resources Research, Chinese Academy of Sciences, Beijing, 100101, China; Earth Critical Zone and Flux Research Station of Xing'an Mountains, Chinese Academy of 15 Sciences, Daxing'anling, 165200, China; College of Resources and Environment, University of Chinese Academy of Sciences, Beijing, 10049, China. Electronic address:
Accurate quantifying of methane (CH) emissions is a critical aspect of current research on regional carbon budgets. However, due to limitations in observational data, research methodologies, and an incomplete understanding of process mechanisms, significant uncertainties persist in the assessment of wetland CH fluxes in China. In this study, we developed a machine learning model by integrating measured CH fluxes with related environmental data to produce a high-resolution (1 km) dataset of CH fluxes from China's wetlands for the period 2000-2020.
View Article and Find Full Text PDFSci Total Environ
January 2025
Research Centre of Ecology & Environment for Coastal Area and Deep Sea, Guangdong University of Technology, Guangzhou 510006, China; Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou), Guangzhou 511458, China; School of Ecology, Environment and Resources, Guangdong University of Technology, Guangzhou 510006, China; Guangdong Basic Research Center of Excellence for Ecological Security and Green Development, Guangdong University of Technology, Guangzhou 510006, China. Electronic address:
Methane leaking from the deep seabed is a primary source of carbon and energy for various microorganisms, sustaining the evolution and productivity of cold seep ecosystems. However, the dynamics of methane hydrate formation under methane seepage conditions and potential impacts on the evolution of cold seep ecosystems remain unclear. This study investigated the dynamic formation characteristics of gas hydrates within cold seep sediments by simulating the methane leakage process.
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