A practical and efficient protocol for synthesis of >99% diastereopure - and -alkenyl nitriles is developed, through tetramethylthiourea-mediated stereospecific deoxygenation of respective - and -cyanoepoxides in ethanol. The desired products are obtained in excellent yields.
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| http://dx.doi.org/10.1021/acs.joc.3c02869 | DOI Listing |
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