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Alkoxy-Functionalized Hydroxamate/Zinc Metal-Organic Frameworks and the Effects of Substituents and Acid Addition on Their Structures. | LitMetric

Alkoxy-Functionalized Hydroxamate/Zinc Metal-Organic Frameworks and the Effects of Substituents and Acid Addition on Their Structures.

Inorg Chem

Department of Chemistry, College of Science, Rikkyo University, 3-34-1 Nishi-ikebukuro, Toshima-ku, Tokyo 171-8501, Japan.

Published: February 2024

Single crystals of alkoxy-functionalized hydroxamate/zinc metal-organic frameworks (MOFs) were obtained by fixating the hydroxamate moiety via intramolecular hydrogen bonding. The resulting MOF structures depend on the steric demand of the alkoxy groups, whereby the incorporation of bulky isopropyl groups affords porous hydroxamate/zinc MOFs. The topological structures of the isopropyl-substituted MOFs could be controlled by adding acid.

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Source
http://dx.doi.org/10.1021/acs.inorgchem.3c03438DOI Listing

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