AI Article Synopsis
- The review discusses advancements in photocatalysis and visible light photochemistry and their effects on synthetic carbohydrate chemistry.
- Key areas explored include photocatalytic glycosylations, radical generation at anomeric and non-anomeric positions, and additions to glycals.
- The article also addresses factors affecting selectivity and mechanistic details of these processes.
Article Abstract
This review article highlights the diverse ways in which recent developments in the areas of photocatalysis and visible light photochemistry are impacting synthetic carbohydrate chemistry. The major topics covered are photocatalytic glycosylations, generation of radicals at the anomeric position, transformations involving radical formation at non-anomeric positions, additions to glycals, processes initiated by photocatalytic hydrogen atom transfer from sugars, and functional group interconversions at OH and SH groups. Factors influencing stereo- and site-selectivity in these processes, along with mechanistic aspects, are discussed.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC10806712 | PMC |
| http://dx.doi.org/10.1039/d3sc05400d | DOI Listing |
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