The use of iron-based catalysts for the water oxidation reaction is highly attractive due to the high abundance of iron. While many molecular catalysts have been made, most show limited activity and short lifetimes. An exception with higher activity was presented by Thummel and co-workers in 2015. Herein we present a study on the feasibility of the coupling of two O centered radicals originating from the two subunits of the dinuclear catalyst. The reaction pathway includes the oxidation to the active species Fe-O-Fe but avoids further high potential oxidations which previous mechanistic proposals have relied on.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d3dt03178k | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
The potential of mangrove leaves extract as a bioactive food ingredient using various water extract.
F1000Res
January 2025
Postgraduate School of Universitas Brawijaya, Universitas Brawijaya, Malang, East Java, 65145, Indonesia.
Background: , known as the red pidada, has been widely utilized by the Indonesian. leaves contain various active compounds, contributing to their popularity in the treatment of various diseases. Mangrove leaves are also known to exhibit very high antioxidant activity.
View Article and Find Full Text PDFCeFe nanofibrous carbon nanozyme integrated with smartphone for the point-of-care testing of norfloxacin in water.
J Pharm Anal
October 2024
School of Chemistry and Chemical Engineering, Nanchang University, Nanchang, 330031, China.
The overuse of antibiotics has led to the severe contamination of water bodies, posing a considerable hazard to human health. Therefore, the development of an accurate and rapid point-of-care testing (POCT) platform for the quantitative detection of antibiotics is necessary. In this study, Cerium oxide (CeO) and Ferrosoferric oxide (FeO) nanoparticles were simultaneously encapsulated into N-doped nanofibrous carbon microspheres to form of a novel nanozyme (CeFe-NCMzyme) with a porous structure, high surface area, and N-doped carbon material properties, leading to a considerable enhancement of the peroxidase (POD)-like activity compared with that of the CeO or FeO nanoparticles alone.
View Article and Find Full Text PDFSoftware-aided efficient identification of the components of compound formulae and their metabolites in rats by UHPLC/IM-QTOF-MS and an in-house high-definition MS library: Sishen formula as a case.
J Pharm Anal
October 2024
National Key Laboratory of Chinese Medicine Modernization, State Key Laboratory of Component-based Chinese Medicine, Tianjin University of Traditional Chinese Medicine, Tianjin, 301617, China.
Identifying the compound formulae-related xenobiotics in bio-samples is full of challenges. Conventional strategies always exhibit the insufficiencies in overall coverage, analytical efficiency, and degree of automation, and the results highly rely on the personal knowledge and experience. The goal of this work was to establish a software-aided approach, by integrating ultra-high performance liquid chromatography/ion-mobility quadrupole time-of-flight mass spectrometry (UHPLC/IM-QTOF-MS) and in-house high-definition MS library, to enhance the identification of prototypes and metabolites of the compound formulae , taking Sishen formula (SSF) as a template.
View Article and Find Full Text PDFPreparation and evaluation of MSR-1 bioinoculant on the growth and productivity of (L.) R. Wilczek.
3 Biotech
February 2025
Marine Biotechnology and Bioproducts Laboratory, Department of Biomedical Sciences, School of Biosciences and Technology, Vellore Institute of Technology, Vellore, 632014 Tamil Nadu India.
Unlabelled: Recently, there has been a growing interest in the application of beneficial microorganisms to enhance crop performance. (MSR-1) are spiral-shaped, gram-negative bacteria that exhibit magnetotaxis with the help of magnetosomes (iron oxide or iron sulphide). They have exhibited biomedical and environmental applications; however, the agricultural utilization of these strains is yet to be explored.
View Article and Find Full Text PDFElucidating the degradation mechanism of beef myofibrillar proteins under hydroxyl radical oxidation through the lens of cysteine oxidation modifications.
Food Chem X
January 2025
Hubei Key Laboratory of Edible Wild Plants Conservation & Utilization, College of Life Sciences, Hubei Normal University, Huangshi 435002, China.
The study aimed to assess the oxidative modification behavior of bovine myofibrillar proteins (MPs) cysteines (Cys) by hydroxyl radical (·OH) through the construction of an in vitr Fenton reaction system. The ·OH generated by the Fenton reaction induced large-scale oxidative modification of Cys, and redox proteomics identified a total of 1192 differential oxidation sites (Dos), 59 Dos were located in the MPs structure. The Cys of actin (17 Dos), myosin/myomesin (16 Dos), tenascin (12 Dos) and sarcomere (10 Dos) in the MPs structure showed active oxidative modification behavior towards ·OH, especially with the "-C-X-X-X-X-W-" structure amino acid sequence showed high sensitivity.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!