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Structure determines performance: isomeric Ti-MOFs for photocatalytic synthesis of hydrogen peroxide. | LitMetric

Structure determines performance: isomeric Ti-MOFs for photocatalytic synthesis of hydrogen peroxide.

Chem Commun (Camb)

School of Environmental Science and Engineering, Qingdao University, Qingdao, 266071, China.

Published: February 2024

NH-UiO-66(Ti) and NH-MIL-125(Ti) were successfully prepared by using post-synthesis exchange (PSE) and hydrothermal methods, and then these frameworks were tested for photocatalytic hydrogen peroxide production in pure water under visible light. NH-MIL-125(Ti) exhibits superior activity compared to NH-UiO-66(Ti) due to its shorter Ti-O bond. In addition, NH-MIL-125-D (defective) demonstrates a high photocatalytic yield of hydrogen peroxide owing to the presence of defect-rich titanium rich sites.

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Source
http://dx.doi.org/10.1039/d3cc05845jDOI Listing

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